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Redox Reactions question

2025 · 4 Apr · Shift 1 · Q24
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Redox Reactions question

2025 · 4 Apr · Shift 1 · Q24

JEE MainChemistryRedox ReactionsNumerical+4 / −1
KMnO4\mathrm{KMnO}_4KMnO4​ acts as an oxidising agent in acidic medium. ' X ' is the difference between the oxidation states of Mn in reactant and product. ' Y ' is the number of ' d ' electrons present in the brown red precipitate formed at the end of the acetate ion test with neutral ferric chloride. The value of X+Y\mathrm{X}+\mathrm{Y}X+Y is ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 10

  1. Find XXX for KMnO4\mathrm{KMnO_4}KMnO4​ in acidic medium

In acidic medium, permanganate ion MnO4−\mathrm{MnO_4^-}MnO4−​ is reduced to Mn2+\mathrm{Mn^{2+}}Mn2+.

  • Oxidation state of Mn in KMnO4\mathrm{KMnO_4}KMnO4​: +7+7+7
  • Oxidation state of Mn in product Mn2+\mathrm{Mn^{2+}}Mn2+: +2+2+2

So, the difference is X=7−2=5X = 7 - 2 = 5X=7−2=5

  1. Find YYY from the acetate ion test with neutral ferric chloride

Acetate ion gives a brown-red precipitate with neutral ferric chloride due to formation of ferric acetate.

Ferric ion is Fe3+\mathrm{Fe^{3+}}Fe3+.

Electronic configuration of Fe: Fe:[Ar]3d64s2\mathrm{Fe}: [Ar]3d^6 4s^2Fe:[Ar]3d64s2

For Fe3+\mathrm{Fe^{3+}}Fe3+:

  • remove two 4s4s4s electrons and one 3d3d3d electron Fe3+:[Ar]3d5\mathrm{Fe^{3+}}: [Ar]3d^5Fe3+:[Ar]3d5

Hence, the number of ddd electrons is Y=5Y = 5Y=5

  1. Compute X+YX+YX+Y

X+Y=5+5=10X+Y = 5+5 = 10X+Y=5+5=10

Therefore, the required integer is 10\boxed{10}10​

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