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Redox Reactions question

2013 · Shift 0 · Q26
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Redox Reactions question

2013 · Shift 0 · Q26

JEE MainChemistryRedox ReactionsMCQ+4 / −1
Consider the following reaction: xMnO4−+yC2O42−xMnO_4^- + yC_2O_4^{2-}xMnO4−​+yC2​O42−​+ zH+H^+H+→\to→ xMn2+Mn^{2+}Mn2+ + 2yCO2CO_2CO2​ +z2H2O{z \over 2}{H_2}O2z​H2​O The value's of x, y and z in the reaction are, respectively :
  1. A
    5, 2 and 16
  2. B
    2, 5 and 8
  3. C
    2, 5 and 16
  4. D
    5, 2 and 8
View written solutionFree

Correct answer: C

  1. Identify the half-reactions in acidic medium

    The reaction is between permanganate and oxalate in acidic medium.

    • Reduction half-reaction: MnO4−+8H++5e−→Mn2++4H2OMnO_4^- + 8H^+ + 5e^- \to Mn^{2+} + 4H_2OMnO4−​+8H++5e−→Mn2++4H2​O

    • Oxidation half-reaction: C2O42−→2CO2+2e−C_2O_4^{2-} \to 2CO_2 + 2e^-C2​O42−​→2CO2​+2e−

  2. Equalize electrons exchanged

    The least common multiple of electrons =10= 10=10.

    • Multiply the manganese half-reaction by 222: 2MnO4−+16H++10e−→2Mn2++8H2O2MnO_4^- + 16H^+ + 10e^- \to 2Mn^{2+} + 8H_2O2MnO4−​+16H++10e−→2Mn2++8H2​O

    • Multiply the oxalate half-reaction by 555: 5C2O42−→10CO2+10e−5C_2O_4^{2-} \to 10CO_2 + 10e^-5C2​O42−​→10CO2​+10e−

  3. Add the half-reactions

    2MnO4−+16H++5C2O42−→2Mn2++8H2O+10CO22MnO_4^- + 16H^+ + 5C_2O_4^{2-} \to 2Mn^{2+} + 8H_2O + 10CO_22MnO4−​+16H++5C2​O42−​→2Mn2++8H2​O+10CO2​

  4. Compare with the given general form

    Given: xMnO4−+yC2O42−+zH+→xMn2++2yCO2+z2H2OxMnO_4^- + yC_2O_4^{2-} + zH^+ \to xMn^{2+} + 2yCO_2 + \frac{z}{2}H_2OxMnO4−​+yC2​O42−​+zH+→xMn2++2yCO2​+2z​H2​O

    From the balanced equation:

    • x=2x = 2x=2
    • y=5y = 5y=5
    • z=16z = 16z=16

    Check:

    • 2y=2(5)=102y = 2(5) = 102y=2(5)=10 gives 10CO210CO_210CO2​ ✔️
    • z2=162=8\dfrac{z}{2} = \dfrac{16}{2} = 82z​=216​=8 gives 8H2O8H_2O8H2​O ✔️
  5. Evaluate options

    • A: (5,2,16)(5,2,16)(5,2,16) ❌
    • B: (2,5,8)(2,5,8)(2,5,8) ❌
    • C: (2,5,16)(2,5,16)(2,5,16) ✅
    • D: (5,2,8)(5,2,8)(5,2,8) ❌

Therefore, the correct answer is Option C.

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