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Redox Reactions question

2016 · 10 Apr · Shift 1 · Q20
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Redox Reactions question

2016 · 10 Apr · Shift 1 · Q20

JEE MainChemistryRedox ReactionsMCQ+4 / −1
The volume of 0.1N dibasic acid sufficient to neutralize 1 g of a base that furnishes 0.04 mole of OH− in aqueous solution is :
  1. A
    200 mL
  2. B
    400 mL
  3. C
    600 mL
  4. D
    800 mL
View written solutionFree

Correct answer: B

  1. Interpret the given data

    We are told that 1 g of the base furnishes 0.040.040.04 mole of OH−\text{OH}^-OH− in aqueous solution.

    So, the total basic equivalents produced by 111 g of the base are: 0.04 equivalent0.04 \text{ equivalent}0.04 equivalent because for hydroxide ion, 1 mole of OH−=1 equivalent1 \text{ mole of } \text{OH}^- = 1 \text{ equivalent}1 mole of OH−=1 equivalent

  2. Condition for neutralization

    In an acid-base neutralization: acid equivalents=base equivalents\text{acid equivalents} = \text{base equivalents}acid equivalents=base equivalents

    Therefore, acid required =0.04= 0.04=0.04 equivalent.

  3. Use normality relation

    The acid is a 0.1 N0.1\text{ N}0.1 N dibasic acid.

    Since normality is already given, we directly use: equivalents=N×V(in L)\text{equivalents} = N \times V(\text{in L})equivalents=N×V(in L)

    Hence, 0.04=0.1×V0.04 = 0.1 \times V0.04=0.1×V

    V=0.040.1=0.4 LV = \frac{0.04}{0.1} = 0.4 \text{ L}V=0.10.04​=0.4 L

  4. Convert to mL

    0.4 L=400 mL0.4 \text{ L} = 400 \text{ mL}0.4 L=400 mL

  5. Check options

    • A: 200200200 mL
    • B: 400400400 mL
    • C: 600600600 mL
    • D: 800800800 mL

    Therefore, the correct option is B.


Comparison with stored answer: Stored correct answer is B, which matches the derived result.

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