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Practical Organic Chemistry question

2024 · 29 Jan · Shift 2 · Q12
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Practical Organic Chemistry question

2024 · 29 Jan · Shift 2 · Q12

JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
Chromatographic technique/s based on the principle of differential adsorption is / are A. Column chromatography B. Thin layer chromatography C. Paper chromatography Choose the most appropriate answer from the options given below:
  1. A
    B only
  2. B
    A only
  3. C
    A & B only
  4. D
    C only
View written solutionFree

Correct answer: C

  1. Identify the principle asked in the question

    The question asks which chromatographic techniques are based on differential adsorption.

    • In adsorption chromatography, separation occurs because different substances are adsorbed to different extents on the surface of a solid stationary phase.
  2. Check each technique

    A. Column chromatography

    • In column chromatography, the stationary phase is usually silica gel or alumina.
    • These are solid adsorbents.
    • Components move at different rates because they are adsorbed differently.

    Hence, A is based on differential adsorption.

    B. Thin layer chromatography (TLC)

    • In TLC, the stationary phase is again usually silica gel or alumina coated on a plate.
    • Separation occurs due to different extents of adsorption of components on the solid surface.

    Hence, B is also based on differential adsorption.

    C. Paper chromatography

    • In paper chromatography, the stationary phase is water held in the fibers of paper.
    • Separation occurs mainly by partition between the stationary liquid phase and the mobile phase.

    Hence, C is not based on differential adsorption.

  3. Conclusion

    Techniques based on differential adsorption are: A and B\boxed{A \text{ and } B}A and B​

  4. Match with the given options

    • Option A: B only
    • Option B: A only
    • Option C: A & B only
    • Option D: C only

    Therefore, the correct option is: Option C\boxed{\text{Option C}}Option C​

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