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Practical Organic Chemistry question

2023 · 8 Apr · Shift 2 · Q4
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Practical Organic Chemistry question

2023 · 8 Apr · Shift 2 · Q4

JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
A compound 'X\mathrm{X}X' when treated with phthalic anhydride in presence of concentrated H2SO4\mathrm{H}_{2} \mathrm{SO}_{4}H2​SO4​ yields 'Y\mathrm{Y}Y'. 'Y\mathrm{Y}Y' is used as an acid/base indicator. 'X\mathrm{X}X' and 'Y\mathrm{Y}Y' are respectively
  1. A
    Toludine, Phenolphthalein
  2. B
    Carbolic acid, Phenolphthalein
  3. C
    Salicylaldehyde, Phenolphthalein
  4. D
    Anisole, methyl orange
View written solutionFree

Correct answer: B

  1. Identify the reaction mentioned

    The question says that compound XXX reacts with phthalic anhydride in presence of concentrated H2SO4\mathrm{H_2SO_4}H2​SO4​ to give YYY, and YYY is used as an acid-base indicator.

  2. Recall the standard preparation of common indicators

    Phenolphthalein is prepared by condensation of phenol (also called carbolic acid) with phthalic anhydride in presence of concentrated sulfuric acid.

    The reaction is: Phenol+Phthalic anhydride→ conc. H2SO4Phenolphthalein\text{Phenol} + \text{Phthalic anhydride} \xrightarrow[\ ]{\mathrm{conc.\ H_2SO_4}} \text{Phenolphthalein}Phenol+Phthalic anhydrideconc. H2​SO4​ ​Phenolphthalein

  3. Match with the options

    • A: Toludine, Phenolphthalein
      Toluidine is an aromatic amine, not the standard reactant for preparing phenolphthalein. So this is incorrect.

    • B: Carbolic acid, Phenolphthalein
      Carbolic acid is another name for phenol. Phenol reacts with phthalic anhydride to form phenolphthalein, which is an acid-base indicator. So this is correct.

    • C: Salicylaldehyde, Phenolphthalein
      Salicylaldehyde does not give phenolphthalein in this reaction. Incorrect.

    • D: Anisole, methyl orange
      Methyl orange is an azo dye indicator, not formed by reacting anisole with phthalic anhydride. Incorrect.

  4. Conclusion

    Therefore, X=Carbolic acid (phenol),Y=PhenolphthaleinX = \text{Carbolic acid (phenol)}, \quad Y = \text{Phenolphthalein}X=Carbolic acid (phenol),Y=Phenolphthalein

    So the correct option is B.

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