JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
In chromyl chloride test for confirmation of ion, a yellow solution is obtained. Acidification of the solution and addition of amyl alcohol and turns organic layer blue indicating formation of chromium pentoxide. The oxidation state of chromium in that is
- A+6
- B+5
- C+3
- D+10
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Correct answer: A
-
In the chromyl chloride test, chloride ion gives chromyl chloride, and after further treatment a yellow solution containing chromium in a high oxidation state is obtained.
-
On acidification and addition of amyl alcohol with , the blue organic layer is due to formation of chromium pentoxide, written as:
-
Let the oxidation state of chromium in be .
-
In , the structure contains:
- one oxo oxygen: oxidation number
- two peroxide groups , i.e. four oxygens each with oxidation number
So total oxidation contribution of oxygen is:
-
Since the molecule is neutral:
-
Therefore, the oxidation state of chromium in chromium pentoxide is:
-
Checking options:
- A: ✅
- B: ❌
- C: ❌
- D: ❌
Hence, the correct option is A.
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