- ABoth and are true and is the correct explanation of .
- BBoth and are true but is NOT the correct explanation of .
- Cis false but is true.
- Dis true but is false.
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Correct answer: A
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Identify the trend in acidity of group 16 hydrides
The hydrides of group 16 are:
Down the group, acidity increases:
Therefore, Assertion A: is true.
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Reason for increase in acidity down the group
As we move down the group, the size of the central atom increases, so the bond between hydrogen and the central atom becomes weaker.
Thus, the bond dissociation enthalpy follows: meaning the bond is easier to break than the bond.
Hence, Reason R: is also true.
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Check whether R explains A
Acidity of these hydrides depends mainly on how easily they can release . A weaker bond means easier proton release.
Since has lower bond dissociation enthalpy than , it donates proton more easily and is therefore more acidic.
So, R is the correct explanation of A.
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Conclusion
Both Assertion and Reason are true, and Reason correctly explains Assertion.
Therefore, the correct option is:
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