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Periodic Table and Periodicity question

2024 · 30 Jan · Shift 2 · Q12
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Periodic Table and Periodicity question

2024 · 30 Jan · Shift 2 · Q12

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R: Assertion A: H2Te\mathrm{H}_2 \mathrm{Te}H2​Te is more acidic than H2 S\mathrm{H}_2 \mathrm{~S}H2​ S. Reason R: Bond dissociation enthalpy of H2Te\mathrm{H}_2 \mathrm{Te}H2​Te is lower than H2 S\mathrm{H}_2 \mathrm{~S}H2​ S. In the light of the above statements, choose the most appropriate from the options given below:
  1. A
    Both AAA and RRR are true and RRR is the correct explanation of AAA.
  2. B
    Both AAA and RRR are true but RRR is NOT the correct explanation of AAA.
  3. C
    AAA is false but RRR is true.
  4. D
    AAA is true but RRR is false.
View written solutionFree

Correct answer: A

  1. Identify the trend in acidity of group 16 hydrides

    The hydrides of group 16 are: H2O, H2S, H2Se, H2Te\mathrm{H_2O,\ H_2S,\ H_2Se,\ H_2Te}H2​O, H2​S, H2​Se, H2​Te

    Down the group, acidity increases: H2O<H2S<H2Se<H2Te\mathrm{H_2O < H_2S < H_2Se < H_2Te}H2​O<H2​S<H2​Se<H2​Te

    Therefore, Assertion A: H2Te is more acidic than H2S\mathrm{H_2Te} \text{ is more acidic than } \mathrm{H_2S}H2​Te is more acidic than H2​S is true.

  2. Reason for increase in acidity down the group

    As we move down the group, the size of the central atom increases, so the bond between hydrogen and the central atom becomes weaker.

    Thus, the bond dissociation enthalpy follows: H−Te<H−S\mathrm{H-Te < H-S}H−Te<H−S meaning the H−Te\mathrm{H-Te}H−Te bond is easier to break than the H−S\mathrm{H-S}H−S bond.

    Hence, Reason R: Bond dissociation enthalpy of H2Te is lower than H2S\text{Bond dissociation enthalpy of } \mathrm{H_2Te} \text{ is lower than } \mathrm{H_2S}Bond dissociation enthalpy of H2​Te is lower than H2​S is also true.

  3. Check whether R explains A

    Acidity of these hydrides depends mainly on how easily they can release H+\mathrm{H^+}H+. A weaker H−E\mathrm{H-E}H−E bond means easier proton release.

    Since H2Te\mathrm{H_2Te}H2​Te has lower bond dissociation enthalpy than H2S\mathrm{H_2S}H2​S, it donates proton more easily and is therefore more acidic.

    So, R is the correct explanation of A.

  4. Conclusion

    Both Assertion and Reason are true, and Reason correctly explains Assertion.

    Therefore, the correct option is: A\boxed{\text{A}}A​

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