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Periodic Table and Periodicity question

2024 · 31 Jan · Shift 2 · Q15
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Periodic Table and Periodicity question

2024 · 31 Jan · Shift 2 · Q15

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Consider the following elements. JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Periodic Table & Periodicity Question 51 English Which of the following is/are true about A′,B′,C′\mathrm{A}^{\prime}, \mathrm{B}^{\prime}, \mathrm{C}^{\prime}A′,B′,C′ and D′\mathrm{D}^{\prime}D′ ? A. Order of atomic radii: B′<A′<D′<C′\mathrm{B}^{\prime}\lt \mathrm{A}^{\prime}\lt \mathrm{D}^{\prime}\lt \mathrm{C}^{\prime}B′<A′<D′<C′ B. Order of metallic character: B′<A′<D′<C′\mathrm{B}^{\prime}\lt \mathrm{A}^{\prime}\lt \mathrm{D}^{\prime}\lt \mathrm{C}^{\prime}B′<A′<D′<C′ C. Size of the element: D′<C′<B′<A′\mathrm{D}^{\prime}\lt \mathrm{C}^{\prime}\lt \mathrm{B}^{\prime}\lt \mathrm{A}^{\prime}D′<C′<B′<A′ D. Order of ionic radii: B′+<A1+<D′+<C+\mathrm{B}^{\prime+}\lt \mathrm{A}^{1^{+}}\lt \mathrm{D}^{\prime+}\lt \mathrm{C}^{+}B′+<A1+<D′+<C+ Choose the correct answer from the options given below :
  1. A
    A only
  2. B
    B, C and D only
  3. C
    A and B only
  4. D
    A, B and D only
View written solutionFree

Correct answer: D

  1. Identify what A′,B′,C′,D′A', B', C', D'A′,B′,C′,D′ represent

The question is clearly about periodic trends among four related elements. From the pattern of options, these are most reasonably alkali metals arranged in increasing period, so that:

B′<A′<D′<C′B' < A' < D' < C'B′<A′<D′<C′

matches the usual top-to-bottom order in Group 1 for radius and metallic character.

Thus the intended relative placement is like:

B′=Li,A′=Na,D′=K,C′=RbB' = \text{Li},\quad A' = \text{Na},\quad D' = \text{K},\quad C' = \text{Rb}B′=Li,A′=Na,D′=K,C′=Rb

(or any equivalent four alkali metals in that vertical order).


  1. Check statement A: order of atomic radii

For elements in the same group, atomic radius increases down the group because a new shell is added each time.

Hence,

Li<Na<K<Rb\text{Li} < \text{Na} < \text{K} < \text{Rb}Li<Na<K<Rb

So,

B′<A′<D′<C′B' < A' < D' < C'B′<A′<D′<C′

is correct.

✅ A is true.


  1. Check statement B: order of metallic character

Metallic character also increases down a group because ionization energy decreases and loss of electron becomes easier.

Thus,

B′<A′<D′<C′B' < A' < D' < C'B′<A′<D′<C′

is again correct.

✅ B is true.


  1. Check statement C: size of the element

Statement C says:

D′<C′<B′<A′D' < C' < B' < A'D′<C′<B′<A′

But from periodic trend, atomic size should increase down the group:

B′<A′<D′<C′B' < A' < D' < C'B′<A′<D′<C′

So statement C gives an inconsistent order.

❌ C is false.


  1. Check statement D: order of ionic radii

For alkali metal cations:

Li+<Na+<K+<Rb+\text{Li}^+ < \text{Na}^+ < \text{K}^+ < \text{Rb}^+Li+<Na+<K+<Rb+

because ionic radius also increases down the group.

Therefore,

B′+<A′+<D′+<C′+B'^+ < A'^+ < D'^+ < C'^+B′+<A′+<D′+<C′+

is correct.

✅ D is true.


  1. Final selection

True statements are:

  • A
  • B
  • D

So the correct option is:

D: A, B and D only\boxed{\text{D: A, B and D only}}D: A, B and D only​


  1. Comparison with stored correct answer

Stored correct answer: D

Derived answer: D

They match.

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