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Haloalkanes and Haloarenes question

2002 · Shift 0 · Q15
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Haloalkanes and Haloarenes question

2002 · Shift 0 · Q15

JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
The reaction : (CH)3C−Br→H2O(CH)3C−OH{(CH)_3}C - Br\xrightarrow{{H_2}O} {(CH)_3}C - OH(CH)3​C−BrH2​O​(CH)3​C−OH
  1. A
    elimination reaction
  2. B
    substitution reaction
  3. C
    free radical reaction
  4. D
    displacement reaction
View written solutionFree

Correct answer: B

  1. Identify the reactant and reagent

    The given reaction is: (CH3)3C−Br→H2O(CH3)3C−OH(CH_3)_3C-Br \xrightarrow{H_2O} (CH_3)_3C-OH(CH3​)3​C−BrH2​O​(CH3​)3​C−OH

    Here, tert-butyl bromide reacts with water to form tert-butyl alcohol.

  2. What change is happening?

    The bromine atom (−Br)(-Br)(−Br) attached to the carbon is replaced by the hydroxyl group (−OH)(-OH)(−OH).

    So, the transformation is: R−Br→R−OHR-Br \rightarrow R-OHR−Br→R−OH

  3. Classify the reaction

    Since one group (BrBrBr) is replaced by another group (OHOHOH), this is a substitution reaction.

    More specifically, tert-butyl bromide in water undergoes nucleophilic substitution (generally via SN1S_N1SN​1 mechanism because tert-butyl carbocation is stable).

  4. Check the options

    • A: elimination reaction — Incorrect, because no alkene is formed.
    • B: substitution reaction — Correct, because BrBrBr is substituted by OHOHOH.
    • C: free radical reaction — Incorrect, no radical conditions are given.
    • D: displacement reaction — Although substitution can also be described as displacement in a broad sense, in standard organic classification for this reaction, the correct term is substitution reaction.
  5. Final answer

    B: substitution reaction\boxed{\text{B: substitution reaction}}B: substitution reaction​

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