JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
Given below are two statements : Statement (I) : Alcohols are formed when alkyl chlorides are treated with aqueous potassium hydroxide by elimination reaction. Statement (II) : In alcoholic potassium hydroxide, alkyl chlorides form alkenes by abstracting the hydrogen from the -carbon. In the light of the above statements, choose the most appropriate answer from the options given below :
- ABoth Statement I and Statement II are incorrect
- BBoth Statement I and Statement II are correct
- CStatement I is incorrect but Statement II is correct
- DStatement I is correct but Statement II is incorrect
View written solutionFree
Correct answer: C
-
Analyze Statement (I)
Statement (I): Alcohols are formed when alkyl chlorides are treated with aqueous potassium hydroxide by elimination reaction.
- When an alkyl chloride reacts with aqueous KOH, the major reaction is nucleophilic substitution, not elimination.
- The hydroxide ion replaces the chloride ion:
- Thus, alcohol is indeed formed, but by substitution reaction, not by elimination.
Therefore, Statement (I) is incorrect.
-
Analyze Statement (II)
Statement (II): In alcoholic potassium hydroxide, alkyl chlorides form alkenes by abstracting the hydrogen from the -carbon.
- In alcoholic KOH, elimination is favored.
- The base removes a hydrogen from the -carbon, and the halogen leaves from the adjacent carbon, leading to formation of a double bond:
- This is -elimination (dehydrohalogenation).
Therefore, Statement (II) is correct.
-
Evaluate the options
- A: Both incorrect False
- B: Both correct False
- C: Statement I incorrect but Statement II correct True
- D: Statement I correct but Statement II incorrect False
-
Final Answer
The correct option is:
-
Comparison with stored answer
- Derived answer: C
- Stored correct answer: C
- They match.
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