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D and F Block Elements question

2022 · 29 Jun · Shift 1 · Q4
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D and F Block Elements question

2022 · 29 Jun · Shift 1 · Q4

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The electronic configuration of Pt (atomic number 78) is :
  1. A
    [Xe] 4f14 5d9 6s1
  2. B
    [Kr] 4f14 5d10
  3. C
    [Xe] 4f14 5d10
  4. D
    [Xe] 4f14 5d8 6s2
View written solutionFree

Correct answer: A

  1. Identify the element and its position

    Platinum, Pt\mathrm{Pt}Pt, has atomic number 787878.

  2. Start from the nearest noble gas core

    The noble gas preceding platinum is xenon, so we begin with: [Xe][\mathrm{Xe}][Xe]

    Xenon accounts for 545454 electrons.

  3. Fill the remaining electrons beyond xenon

    Total electrons left after [Xe][\mathrm{Xe}][Xe]: 78−54=2478 - 54 = 2478−54=24

    After xenon, electrons enter the orbitals in the sequence involving 4f4f4f, 5d5d5d, and 6s6s6s.

    First fill 4f4f4f: 4f144f^{14}4f14 Electrons used so far beyond xenon: 141414

    Remaining: 24−14=1024 - 14 = 1024−14=10

  4. Expected and actual configuration

    A naive filling might suggest: [Xe] 4f145d86s2[\mathrm{Xe}]\,4f^{14}5d^8 6s^2[Xe]4f145d86s2 But platinum is one of the transition elements that shows an anomalous configuration because a more stable arrangement is obtained by promoting one 6s6s6s electron into the 5d5d5d subshell.

    Hence the actual ground-state configuration is: [Xe] 4f145d96s1[\mathrm{Xe}]\,4f^{14}5d^9 6s^1[Xe]4f145d96s1

  5. Check the options

    • A: [Xe] 4f145d96s1[\mathrm{Xe}]\,4f^{14}5d^9 6s^1[Xe]4f145d96s1 ✅
    • B: [Kr] 4f145d10[\mathrm{Kr}]\,4f^{14}5d^{10}[Kr]4f145d10 ❌ Wrong noble gas core and incomplete representation
    • C: [Xe] 4f145d10[\mathrm{Xe}]\,4f^{14}5d^{10}[Xe]4f145d10 ❌ Missing 6s6s6s electron count properly for neutral Pt
    • D: [Xe] 4f145d86s2[\mathrm{Xe}]\,4f^{14}5d^8 6s^2[Xe]4f145d86s2 ❌ Aufbau expectation, but not the actual ground state
  6. Final answer

    Therefore, the electronic configuration of platinum is: [Xe] 4f145d96s1[\mathrm{Xe}]\,4f^{14}5d^9 6s^1[Xe]4f145d96s1

    So, Option A is correct.

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