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D and F Block Elements question

2021 · 1 Sep · Shift 2 · Q14
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D and F Block Elements question

2021 · 1 Sep · Shift 2 · Q14

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Identify the element for which electronic configuration in +3 oxidation state is [Ar]3d53d_53d5​ :
  1. A
    Ru
  2. B
    Mn
  3. C
    Co
  4. D
    Fe
View written solutionFree

Correct answer: D

  1. We need the element whose electronic configuration in the +3+3+3 oxidation state is [Ar]3d5[Ar]3d^5[Ar]3d5

  2. In transition metals, electrons are removed first from the 4s4s4s orbital and then from the 3d3d3d orbital.

  3. Check each option:

Option A: Ru

Ruthenium (Z=44Z=44Z=44) has configuration approximately [Kr]4d75s1[Kr]4d^75s^1[Kr]4d75s1 After removing 3 electrons, it cannot give [Ar]3d5[Ar]3d^5[Ar]3d5. So, A is incorrect.

Option B: Mn

Manganese (Z=25Z=25Z=25) has ground-state configuration [Ar]3d54s2[Ar]3d^54s^2[Ar]3d54s2 For Mn3+Mn^{3+}Mn3+, remove two 4s4s4s electrons and one 3d3d3d electron: Mn3+=[Ar]3d4Mn^{3+}=[Ar]3d^4Mn3+=[Ar]3d4 So, B is incorrect.

Option C: Co

Cobalt (Z=27Z=27Z=27) has ground-state configuration [Ar]3d74s2[Ar]3d^74s^2[Ar]3d74s2 For Co3+Co^{3+}Co3+: Co3+=[Ar]3d6Co^{3+}=[Ar]3d^6Co3+=[Ar]3d6 So, C is incorrect.

Option D: Fe

Iron (Z=26Z=26Z=26) has ground-state configuration [Ar]3d64s2[Ar]3d^64s^2[Ar]3d64s2 For Fe3+Fe^{3+}Fe3+, remove two 4s4s4s electrons and one 3d3d3d electron: Fe3+=[Ar]3d5Fe^{3+}=[Ar]3d^5Fe3+=[Ar]3d5 So, D is correct.

  1. Therefore, the element is Fe\boxed{Fe}Fe​

  2. Comparison with stored correct answer:

  • Stored correct answer: D
  • Derived answer: D
  • They agree.
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