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D and F Block Elements question

2021 · 16 Mar · Shift 2 · Q9
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D and F Block Elements question

2021 · 16 Mar · Shift 2 · Q9

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Fex2 and Fey3 are known when x and y are :
  1. A
    x = F, Cl, Br, I and y = F, Cl, Br, I
  2. B
    x = F, Cl, Br and y = F, Cl, Br, I
  3. C
    x = F, Cl, Br, I and y = F, Cl, Br
  4. D
    x = Cl, Br, I and y = F, Cl, Br, I
View written solutionFree

Correct answer: C

  1. We need to identify for which halogens iron forms:

    • FeX2\mathrm{FeX_2}FeX2​
    • FeY3\mathrm{FeY_3}FeY3​
  2. Iron commonly shows oxidation states +2+2+2 and +3+3+3.

    • In FeX2\mathrm{FeX_2}FeX2​, iron is in the +2+2+2 state.
    • In FeY3\mathrm{FeY_3}FeY3​, iron is in the +3+3+3 state.
  3. Now check iron halides:

    Ferrous halides, FeX2\mathrm{FeX_2}FeX2​:

    • FeF2\mathrm{FeF_2}FeF2​ exists
    • FeCl2\mathrm{FeCl_2}FeCl2​ exists
    • FeBr2\mathrm{FeBr_2}FeBr2​ exists
    • FeI2\mathrm{FeI_2}FeI2​ exists

    So, for xxx, all halogens F,Cl,Br,I\mathrm{F, Cl, Br, I}F,Cl,Br,I are possible.

  4. Ferric halides, FeY3\mathrm{FeY_3}FeY3​:

    • FeF3\mathrm{FeF_3}FeF3​ exists
    • FeCl3\mathrm{FeCl_3}FeCl3​ exists
    • FeBr3\mathrm{FeBr_3}FeBr3​ exists
    • FeI3\mathrm{FeI_3}FeI3​ does not exist as a stable compound

    Reason: I−\mathrm{I^-}I− is a good reducing agent and reduces Fe3+\mathrm{Fe^{3+}}Fe3+ to Fe2+\mathrm{Fe^{2+}}Fe2+, while itself gets oxidized to iodine: 2Fe3++2I−→2Fe2++I22\mathrm{Fe^{3+}} + 2\mathrm{I^-} \rightarrow 2\mathrm{Fe^{2+}} + \mathrm{I_2}2Fe3++2I−→2Fe2++I2​ Hence FeI3\mathrm{FeI_3}FeI3​ is not known.

  5. Therefore:

    • x=F,Cl,Br,Ix = \mathrm{F, Cl, Br, I}x=F,Cl,Br,I
    • y=F,Cl,Bry = \mathrm{F, Cl, Br}y=F,Cl,Br
  6. Matching with the options:

    • Option C: x=F,Cl,Br,Ix = \mathrm{F, Cl, Br, I}x=F,Cl,Br,I and y=F,Cl,Bry = \mathrm{F, Cl, Br}y=F,Cl,Br

    So, Option C is correct.

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