- ACe (At. No. 58)
- BLa (At. No. 57)
- CLu (At. No. 71)
- DGd (At. No. 64)
View written solutionFree
Correct answer: A
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General oxidation state of lanthanoids
The most common oxidation state of lanthanoids is because they usually lose two electrons and one electron.
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When do lanthanoids deviate from ?
Deviation from occurs when some other oxidation state gives an especially stable electronic configuration, such as:
- empty subshell:
- half-filled subshell:
- fully filled subshell:
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Check the given elements
A: Ce
Cerium has configuration approximately: In the state: In the state: Since (empty subshell) is especially stable, cerium readily shows in addition to .
So, Ce easily deviates from .
B: La
Lanthanum strongly prefers and does not commonly show other oxidation states.
C: Lu
The state itself gives the very stable fully filled configuration, so it does not tend to deviate easily.
D: Gd
The state gives the very stable half-filled configuration, so it also prefers .
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Conclusion
Among the given options, cerium most readily deviates from the common oxidation state because attains the stable configuration.
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