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D and F Block Elements question

2022 · 26 Jun · Shift 2 · Q6
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D and F Block Elements question

2022 · 26 Jun · Shift 2 · Q6

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The most common oxidation state of Lanthanoid elements is +3. Which of the following is likely to deviate easily from +3 oxidation state?
  1. A
    Ce (At. No. 58)
  2. B
    La (At. No. 57)
  3. C
    Lu (At. No. 71)
  4. D
    Gd (At. No. 64)
View written solutionFree

Correct answer: A

  1. General oxidation state of lanthanoids

    The most common oxidation state of lanthanoids is +3+3+3 because they usually lose two 6s6s6s electrons and one 5d/4f5d/4f5d/4f electron.

  2. When do lanthanoids deviate from +3+3+3?

    Deviation from +3+3+3 occurs when some other oxidation state gives an especially stable electronic configuration, such as:

    • empty 4f4f4f subshell: 4f04f^04f0
    • half-filled 4f4f4f subshell: 4f74f^74f7
    • fully filled 4f4f4f subshell: 4f144f^{14}4f14
  3. Check the given elements

    A: Ce (Z=58)(Z=58)(Z=58)

    Cerium has configuration approximately: [Xe]4f15d16s2[Xe]4f^1 5d^1 6s^2[Xe]4f15d16s2 In the +3+3+3 state: Ce3+:[Xe]4f1Ce^{3+} : [Xe]4f^1Ce3+:[Xe]4f1 In the +4+4+4 state: Ce4+:[Xe]4f0Ce^{4+} : [Xe]4f^0Ce4+:[Xe]4f0 Since 4f04f^04f0 (empty fff subshell) is especially stable, cerium readily shows +4+4+4 in addition to +3+3+3.

    So, Ce easily deviates from +3+3+3.

    B: La (Z=57)(Z=57)(Z=57)

    La:[Xe]5d16s2La : [Xe]5d^1 6s^2La:[Xe]5d16s2 La3+:[Xe]La^{3+} : [Xe]La3+:[Xe] Lanthanum strongly prefers +3+3+3 and does not commonly show other oxidation states.

    C: Lu (Z=71)(Z=71)(Z=71)

    Lu:[Xe]4f145d16s2Lu : [Xe]4f^{14}5d^1 6s^2Lu:[Xe]4f145d16s2 Lu3+:[Xe]4f14Lu^{3+} : [Xe]4f^{14}Lu3+:[Xe]4f14 The +3+3+3 state itself gives the very stable fully filled 4f144f^{14}4f14 configuration, so it does not tend to deviate easily.

    D: Gd (Z=64)(Z=64)(Z=64)

    Gd:[Xe]4f75d16s2Gd : [Xe]4f^7 5d^1 6s^2Gd:[Xe]4f75d16s2 Gd3+:[Xe]4f7Gd^{3+} : [Xe]4f^7Gd3+:[Xe]4f7 The +3+3+3 state gives the very stable half-filled 4f74f^74f7 configuration, so it also prefers +3+3+3.

  4. Conclusion

    Among the given options, cerium most readily deviates from the common +3+3+3 oxidation state because Ce4+Ce^{4+}Ce4+ attains the stable 4f04f^04f0 configuration.

A: Ce\boxed{\text{A: Ce}}A: Ce​

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