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D and F Block Elements question

2022 · 27 Jul · Shift 2 · Q6
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D and F Block Elements question

2022 · 27 Jul · Shift 2 · Q6

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
In neutral or alkaline solution, MnO4−\mathrm{MnO}_{4}^{-}MnO4−​ oxidises thiosulphate to :
  1. A
    S2O72−\mathrm{S}_{2} \mathrm{O}_{7}^{2-}S2​O72−​
  2. B
    S2O82−\mathrm{S}_{2} \mathrm{O}_{8}^{2-}S2​O82−​
  3. C
    SO32−\mathrm{SO}_{3}^{2-}SO32−​
  4. D
    SO42−\mathrm{SO}_{4}^{2-}SO42−​
View written solutionFree

Correct answer: D

  1. We need to identify the product formed when thiosulphate ion, S2O32−\mathrm{S_2O_3^{2-}}S2​O32−​, is oxidised by permanganate, MnO4−\mathrm{MnO_4^-}MnO4−​, in neutral or alkaline medium.

  2. In neutral/alkaline solution, permanganate is a strong oxidising agent and commonly gets reduced as: MnO4−+2H2O+3e−→MnO2+4OH−\mathrm{MnO_4^- + 2H_2O + 3e^- \rightarrow MnO_2 + 4OH^-}MnO4−​+2H2​O+3e−→MnO2​+4OH− This means it can oxidise thiosulphate significantly.

  3. Let us examine the oxidation state change in thiosulphate:

  • In S2O32−\mathrm{S_2O_3^{2-}}S2​O32−​, the two sulphur atoms are not equivalent.
  • On strong oxidation, thiosulphate is converted to sulphate, SO42−\mathrm{SO_4^{2-}}SO42−​.

A standard oxidation half-reaction for thiosulphate to sulphate in alkaline/neutral conditions is: S2O32−+10OH−→2SO42−+5H2O+8e−\mathrm{S_2O_3^{2-} + 10OH^- \rightarrow 2SO_4^{2-} + 5H_2O + 8e^-}S2​O32−​+10OH−→2SO42−​+5H2​O+8e− This shows that the oxidation product is clearly SO42−\mathrm{SO_4^{2-}}SO42−​.

  1. Now check the options:
  • A: S2O72−\mathrm{S_2O_7^{2-}}S2​O72−​ — pyrosulphate; not the usual oxidation product here.
  • B: S2O82−\mathrm{S_2O_8^{2-}}S2​O82−​ — peroxodisulphate; formed by electrochemical oxidation, not by this reaction.
  • C: SO32−\mathrm{SO_3^{2-}}SO32−​ — sulphite is a lower oxidation state product, so not an oxidation product of thiosulphate under strong oxidising conditions.
  • D: SO42−\mathrm{SO_4^{2-}}SO42−​ — correct.
  1. Therefore, in neutral or alkaline solution, MnO4−\mathrm{MnO_4^-}MnO4−​ oxidises thiosulphate to: SO42−\boxed{\mathrm{SO_4^{2-}}}SO42−​​
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