JEE MainChemistryD and F Block ElementsMCQ+4 / −1
In neutral or alkaline solution, oxidises thiosulphate to :
- A
- B
- C
- D
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Correct answer: D
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We need to identify the product formed when thiosulphate ion, , is oxidised by permanganate, , in neutral or alkaline medium.
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In neutral/alkaline solution, permanganate is a strong oxidising agent and commonly gets reduced as: This means it can oxidise thiosulphate significantly.
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Let us examine the oxidation state change in thiosulphate:
- In , the two sulphur atoms are not equivalent.
- On strong oxidation, thiosulphate is converted to sulphate, .
A standard oxidation half-reaction for thiosulphate to sulphate in alkaline/neutral conditions is: This shows that the oxidation product is clearly .
- Now check the options:
- A: — pyrosulphate; not the usual oxidation product here.
- B: — peroxodisulphate; formed by electrochemical oxidation, not by this reaction.
- C: — sulphite is a lower oxidation state product, so not an oxidation product of thiosulphate under strong oxidising conditions.
- D: — correct.
- Therefore, in neutral or alkaline solution, oxidises thiosulphate to:
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