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D and F Block Elements question

2022 · 26 Jun · Shift 1 · Q16
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D and F Block Elements question

2022 · 26 Jun · Shift 1 · Q16

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
The spin-only magnetic moment value of the most basic oxide of vanadium among V2O3V_2O_3V2​O3​, V2O4V_2O_4V2​O4​ and V2O5V_2O_5V2​O5​ is ‾\underline{\hspace{2cm}}​ B.M. (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 3

  1. Identify the most basic oxide of vanadium

For transition metal oxides, basic character decreases with increase in oxidation state.

Given oxides:

  • V2O3V_2O_3V2​O3​ : vanadium is in +3+3+3 oxidation state
  • V2O4V_2O_4V2​O4​ : vanadium is in +4+4+4 oxidation state
  • V2O5V_2O_5V2​O5​ : vanadium is in +5+5+5 oxidation state

Hence, the most basic oxide is: V2O3V_2O_3V2​O3​

  1. Find the electronic configuration of vanadium in V2O3V_2O_3V2​O3​

In V2O3V_2O_3V2​O3​, each vanadium is V3+V^{3+}V3+.

Atomic number of vanadium = 23

Neutral vanadium: V:[Ar] 3d34s2V: [Ar] \, 3d^3 4s^2V:[Ar]3d34s2

For V3+V^{3+}V3+, remove two 4s4s4s electrons and one 3d3d3d electron: V3+:[Ar] 3d2V^{3+}: [Ar] \, 3d^2V3+:[Ar]3d2

So, number of unpaired electrons: n=2n = 2n=2

  1. Calculate spin-only magnetic moment

Formula: μ=n(n+2) B.M.\mu = \sqrt{n(n+2)} \, \text{B.M.}μ=n(n+2)​B.M.

Substitute n=2n=2n=2: μ=2(2+2)=8=22≈2.83 B.M.\mu = \sqrt{2(2+2)} = \sqrt{8} = 2\sqrt{2} \approx 2.83 \, \text{B.M.}μ=2(2+2)​=8​=22​≈2.83B.M.

Nearest integer: 333

  1. Final answer

The spin-only magnetic moment is: 3\boxed{3}3​

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