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D and F Block Elements question

2022 · 26 Jul · Shift 2 · Q17
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D and F Block Elements question

2022 · 26 Jul · Shift 2 · Q17

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
The spin-only magnetic moment value of the compound with strongest oxidizing ability among MnF4,MnF3\mathrm{MnF}_{4}, \mathrm{MnF}_{3}MnF4​,MnF3​ and MnF2\mathrm{MnF}_{2}MnF2​ is ‾\underline{\hspace{2cm}}​ B.M. [nearest integer]
Numerical answer
View written solutionFree

Correct answer: 4

  1. Find oxidation states of Mn in each compound
  • In MnF2\mathrm{MnF_2}MnF2​: fluorine is −1-1−1, so x+2(−1)=0⇒x=+2x + 2(-1) = 0 \Rightarrow x = +2x+2(−1)=0⇒x=+2 Hence Mn is Mn2+\mathrm{Mn^{2+}}Mn2+.

  • In MnF3\mathrm{MnF_3}MnF3​: x+3(−1)=0⇒x=+3x + 3(-1) = 0 \Rightarrow x = +3x+3(−1)=0⇒x=+3 Hence Mn is Mn3+\mathrm{Mn^{3+}}Mn3+.

  • In MnF4\mathrm{MnF_4}MnF4​: x+4(−1)=0⇒x=+4x + 4(-1) = 0 \Rightarrow x = +4x+4(−1)=0⇒x=+4 Hence Mn is Mn4+\mathrm{Mn^{4+}}Mn4+.

  1. Identify which has the strongest oxidizing ability

An oxidizing agent gets reduced. For manganese fluorides, the compound with the highest oxidation state of Mn will have the greatest tendency to get reduced, hence the strongest oxidizing ability.

Therefore, among MnF2,MnF3,MnF4\mathrm{MnF_2}, \mathrm{MnF_3}, \mathrm{MnF_4}MnF2​,MnF3​,MnF4​, the strongest oxidizing agent is: MnF4\mathrm{MnF_4}MnF4​

  1. Find electronic configuration of Mn in MnF4\mathrm{MnF_4}MnF4​

Atomic number of Mn is 252525.

Neutral Mn: Mn:[Ar] 3d54s2\mathrm{Mn}: [Ar] \, 3d^5 4s^2Mn:[Ar]3d54s2

For Mn4+\mathrm{Mn^{4+}}Mn4+, remove two 4s4s4s electrons and two 3d3d3d electrons: Mn4+:[Ar] 3d3\mathrm{Mn^{4+}}: [Ar] \, 3d^3Mn4+:[Ar]3d3

So number of unpaired electrons, n=3n = 3n=3

  1. Calculate spin-only magnetic moment

Spin-only magnetic moment is: μ=n(n+2) B.M.\mu = \sqrt{n(n+2)} \text{ B.M.}μ=n(n+2)​ B.M.

Substitute n=3n=3n=3: μ=3(3+2)=15≈3.87 B.M.\mu = \sqrt{3(3+2)} = \sqrt{15} \approx 3.87 \text{ B.M.}μ=3(3+2)​=15​≈3.87 B.M.

Nearest integer: 444

  1. Compare with stored answer

Stored correct answer is 555, but the calculated value is 444 (nearest integer).

So the stored answer does not agree with the correct spin-only value for the strongest oxidizing compound.

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