JEE MainChemistryD and F Block ElementsNumerical+4 / −1
The spin-only magnetic moment value of the compound with strongest oxidizing ability among and is B.M. [nearest integer]
Numerical answer
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Correct answer: 4
- Find oxidation states of Mn in each compound
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In : fluorine is , so Hence Mn is .
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In : Hence Mn is .
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In : Hence Mn is .
- Identify which has the strongest oxidizing ability
An oxidizing agent gets reduced. For manganese fluorides, the compound with the highest oxidation state of Mn will have the greatest tendency to get reduced, hence the strongest oxidizing ability.
Therefore, among , the strongest oxidizing agent is:
- Find electronic configuration of Mn in
Atomic number of Mn is .
Neutral Mn:
For , remove two electrons and two electrons:
So number of unpaired electrons,
- Calculate spin-only magnetic moment
Spin-only magnetic moment is:
Substitute :
Nearest integer:
- Compare with stored answer
Stored correct answer is , but the calculated value is (nearest integer).
So the stored answer does not agree with the correct spin-only value for the strongest oxidizing compound.
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