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Coordination Compounds question

2022 · 27 Jun · Shift 1 · Q17
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Coordination Compounds question

2022 · 27 Jun · Shift 1 · Q17

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
Acidified potassium permanganate solution oxidises oxalic acid. The spin-only magnetic moment of the manganese product formed from the above reaction is ‾\underline{\hspace{2cm}}​ B.M. (Nearest integer)
Numerical answer
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Correct answer: 6

  1. Identify the manganese product in the reaction

Acidified potassium permanganate contains the permanganate ion, MnO4−\mathrm{MnO_4^-}MnO4−​, where manganese is in the +7+7+7 oxidation state.

In acidic medium, permanganate oxidises oxalic acid to carbon dioxide and itself gets reduced as:

MnO4−+8H++5e−→Mn2++4H2O\mathrm{MnO_4^- + 8H^+ + 5e^- \rightarrow Mn^{2+} + 4H_2O}MnO4−​+8H++5e−→Mn2++4H2​O

So, the manganese product formed is Mn2+\mathrm{Mn^{2+}}Mn2+.


  1. Find the electronic configuration of Mn2+\mathrm{Mn^{2+}}Mn2+

Atomic number of Mn =25= 25=25.

Neutral manganese:

Mn:[Ar] 3d54s2\mathrm{Mn} : [Ar] \, 3d^5 4s^2Mn:[Ar]3d54s2

For Mn2+\mathrm{Mn^{2+}}Mn2+, remove two electrons from 4s4s4s first:

Mn2+:[Ar] 3d5\mathrm{Mn^{2+}} : [Ar] \, 3d^5Mn2+:[Ar]3d5

Thus, number of unpaired electrons,

n=5n = 5n=5


  1. Use the spin-only magnetic moment formula

μ=n(n+2) B.M.\mu = \sqrt{n(n+2)} \text{ B.M.}μ=n(n+2)​ B.M.

Substituting n=5n=5n=5:

μ=5(5+2)=35\mu = \sqrt{5(5+2)} = \sqrt{35}μ=5(5+2)​=35​

μ≈5.92 B.M.\mu \approx 5.92 \text{ B.M.}μ≈5.92 B.M.

Nearest integer:

666


  1. Compare with stored correct answer

Derived answer =6= 6=6

Stored correct answer =6= 6=6

They match.

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