- Ahave good -accepting character
- Bhave good -donor character
- Care having good -donating ability
- Dare having poor -donating ability
View written solutionFree
Correct answer: A
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Key idea: stabilization of low oxidation states
Metals in low oxidation states are electron-rich. Such metals are stabilized by ligands that can accept electron density from the metal.
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Role of -acceptor ligands
Ligands with good -accepting character have vacant orbitals. They can accept electron density from filled metal -orbitals through back-bonding:
This removes excess electron density from the metal and therefore stabilizes the metal in a low oxidation state.
Examples: CO, CN, phosphines.
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Examine each option
A: have good -accepting character
This is correct, because -acceptor ligands stabilize electron-rich, low oxidation state metals by back-bonding.B: have good -donor character
Strong -donor ligands donate more electron density to the metal, which generally favors higher electron density on the metal and does not specifically stabilize low oxidation states as effectively as -acceptors.C: are having good -donating ability
-donor ligands donate electron density to the metal, which is more suitable for stabilizing metals in higher oxidation states, not lower ones.D: are having poor -donating ability
Poor donation does not provide the key stabilization needed. The important factor is acceptance of electron density by back-bonding, not weak donation. -
Conclusion
Therefore, low oxidation states of metals are common when ligands:
So the correct option is A.
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