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Coordination Compounds question

2022 · 27 Jul · Shift 2 · Q7
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  5. /2022 · 27 Jul · Shift 2 · Q7

Coordination Compounds question

2022 · 27 Jul · Shift 2 · Q7

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Low oxidation state of metals in their complexes are common when ligands :
  1. A
    have good π\piπ-accepting character
  2. B
    have good σ\sigmaσ-donor character
  3. C
    are having good π\piπ-donating ability
  4. D
    are having poor σ\sigmaσ-donating ability
View written solutionFree

Correct answer: A

  1. Key idea: stabilization of low oxidation states

    Metals in low oxidation states are electron-rich. Such metals are stabilized by ligands that can accept electron density from the metal.

  2. Role of π\piπ-acceptor ligands

    Ligands with good π\piπ-accepting character have vacant π∗\pi^*π∗ orbitals. They can accept electron density from filled metal ddd-orbitals through back-bonding:

    M(dπ)→L(π∗)M(d\pi) \to L(\pi^*)M(dπ)→L(π∗)

    This removes excess electron density from the metal and therefore stabilizes the metal in a low oxidation state.

    Examples: CO, CN−^-−, phosphines.

  3. Examine each option

    A: have good π\piπ-accepting character
    This is correct, because π\piπ-acceptor ligands stabilize electron-rich, low oxidation state metals by back-bonding.

    B: have good σ\sigmaσ-donor character
    Strong σ\sigmaσ-donor ligands donate more electron density to the metal, which generally favors higher electron density on the metal and does not specifically stabilize low oxidation states as effectively as π\piπ-acceptors.

    C: are having good π\piπ-donating ability
    π\piπ-donor ligands donate electron density to the metal, which is more suitable for stabilizing metals in higher oxidation states, not lower ones.

    D: are having poor σ\sigmaσ-donating ability
    Poor σ\sigmaσ donation does not provide the key stabilization needed. The important factor is acceptance of electron density by back-bonding, not weak donation.

  4. Conclusion

    Therefore, low oxidation states of metals are common when ligands:

    have good π-accepting character\boxed{\text{have good } \pi\text{-accepting character}}have good π-accepting character​

So the correct option is A.

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