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Correct answer: 1
- We first identify the Werner coordination formulas for each compound.
For cobalt(III), the coordination number is typically .
- Analyze each complex.
(a)
This corresponds to the complex: Here, the coordination sphere has and , i.e. an octahedral complex of type: Such octahedral complexes show cis-trans isomerism.
So, (a) shows cis-trans isomerism.
(b)
This corresponds to: This is an octahedral complex of type: Such complexes do not show cis-trans isomerism because there is only one ligand of type .
So, (b) does not show cis-trans isomerism.
(c)
This corresponds to: This is of type: All ligands are identical, so no geometrical isomerism is possible.
So, (c) does not show cis-trans isomerism.
(d)
Total anions outside/inside must satisfy coordination number for . This gives the complex as: or But in either case, the coordination sphere is of type .
An octahedral complex does not show cis-trans isomerism.
So, (d) does not show cis-trans isomerism.
- Count the number of complexes showing cis-trans form.
Only (a) shows cis-trans isomerism.
Therefore, the required number is:
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