JEE MainChemistryCoordination CompoundsNumerical+4 / −1
1 mol of an octahedral metal complex with formula . 2 on reaction with excess of gives 1 mol of . The denticity of Ligand is . (Integer answer)
Numerical answer
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Correct answer: 2
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We are given an octahedral complex of formula and on reaction with excess , mol of is formed per mol of complex.
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precipitates only the chloride ions present outside the coordination sphere as free counter ions.
Since mol of complex gives mol of , there is exactly one free outside the coordination sphere.
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Total chlorides in the formula = . Therefore:
- chloride is outside the coordination sphere.
- Remaining chlorides are inside the coordination sphere as ligands.
So the complex can be written as
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The complex is stated to be octahedral, so the coordination number of the metal is .
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Inside the coordination sphere:
- chloride ligands are present, each monodentate, contributing coordination sites.
- There are ligands , each of denticity .
Hence total coordination number is
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Solving:
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Therefore, ligand is bidentate.
Final integer answer:
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