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Coordination Compounds question

2021 · 27 Aug · Shift 1 · Q17
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  5. /2021 · 27 Aug · Shift 1 · Q17

Coordination Compounds question

2021 · 27 Aug · Shift 1 · Q17

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
1 mol of an octahedral metal complex with formula MCl3MCl_3MCl3​ . 2LLL on reaction with excess of AgNO3AgNO_3AgNO3​ gives 1 mol of AgClAgClAgCl. The denticity of Ligand LLL is ‾\underline{\hspace{2cm}}​. (Integer answer)
Numerical answer
View written solutionFree

Correct answer: 2

  1. We are given an octahedral complex of formula MCl3⋅2LMCl_3\cdot 2LMCl3​⋅2L and on reaction with excess AgNO3AgNO_3AgNO3​, 111 mol of AgClAgClAgCl is formed per mol of complex.

  2. AgNO3AgNO_3AgNO3​ precipitates only the chloride ions present outside the coordination sphere as free counter ions.

    Since 111 mol of complex gives 111 mol of AgClAgClAgCl, there is exactly one free Cl−Cl^-Cl− outside the coordination sphere.

  3. Total chlorides in the formula = 333. Therefore:

    • 111 chloride is outside the coordination sphere.
    • Remaining 222 chlorides are inside the coordination sphere as ligands.

    So the complex can be written as [MCl2L2]Cl[MCl_2L_2]Cl[MCl2​L2​]Cl

  4. The complex is stated to be octahedral, so the coordination number of the metal is 666.

  5. Inside the coordination sphere:

    • 222 chloride ligands are present, each monodentate, contributing 222 coordination sites.
    • There are 222 ligands LLL, each of denticity ddd.

    Hence total coordination number is 2+2d=62 + 2d = 62+2d=6

  6. Solving: 2d=42d = 42d=4 d=2d = 2d=2

  7. Therefore, ligand LLL is bidentate.

Final integer answer: 222

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