JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The number of stereoisomers possible for is . [ox = oxalate]
Numerical answer
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Correct answer: 3
- Identify the coordination geometry
The complex is where each (oxalate) is a bidentate ligand.
- Two oxalate ligands occupy coordination sites.
- and are monodentate ligands, occupying 1 site each.
So total coordination number is 6, hence the complex is octahedral.
- Type of octahedral complex
This is of the form: where:
- = symmetrical bidentate ligand (oxalate)
For octahedral complexes of type , geometrical isomerism is possible depending on whether and are cis or trans.
- Geometrical isomers
(i) cis isomer
Here and are adjacent.
For , the cis form is optically active because it lacks a plane/center of symmetry. Hence it exists as a pair of enantiomers:
- one form
- one form
So cis gives 2 stereoisomers.
(ii) trans isomer
Here and are opposite to each other.
The trans form has sufficient symmetry and is optically inactive, so it gives only 1 stereoisomer.
- Total number of stereoisomers
Therefore,
- Final answer
- Comparison with stored correct answer
Stored correct answer =
Our derived answer =
So the stored answer is correct.
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