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Coordination Compounds question

2021 · 26 Feb · Shift 2 · Q23
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  5. /2021 · 26 Feb · Shift 2 · Q23

Coordination Compounds question

2021 · 26 Feb · Shift 2 · Q23

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The number of stereoisomers possible for [Co(ox)2(Br)(NH3)]2−[Co(ox)_2(Br)(NH_3)]^{2-}[Co(ox)2​(Br)(NH3​)]2− is ‾\underline{\hspace{2cm}}​. [ox = oxalate]
Numerical answer
View written solutionFree

Correct answer: 3

  1. Identify the coordination geometry

The complex is [Co(ox)2(Br)(NH3)]2−[Co(ox)_2(Br)(NH_3)]^{2-}[Co(ox)2​(Br)(NH3​)]2− where each oxoxox (oxalate) is a bidentate ligand.

  • Two oxalate ligands occupy 2×2=42\times 2 = 42×2=4 coordination sites.
  • Br−Br^-Br− and NH3NH_3NH3​ are monodentate ligands, occupying 1 site each.

So total coordination number is 6, hence the complex is octahedral.


  1. Type of octahedral complex

This is of the form: [M(AA)2ab][M(AA)_2ab][M(AA)2​ab] where:

  • AAAAAA = symmetrical bidentate ligand (oxalate)
  • a=Bra = Bra=Br
  • b=NH3b = NH_3b=NH3​

For octahedral complexes of type [M(AA)2ab][M(AA)_2ab][M(AA)2​ab], geometrical isomerism is possible depending on whether aaa and bbb are cis or trans.


  1. Geometrical isomers

(i) cis isomer

Here BrBrBr and NH3NH_3NH3​ are adjacent.

For [M(AA)2ab][M(AA)_2ab][M(AA)2​ab], the cis form is optically active because it lacks a plane/center of symmetry. Hence it exists as a pair of enantiomers:

  • one Δ\DeltaΔ form
  • one Λ\LambdaΛ form

So cis gives 2 stereoisomers.

(ii) trans isomer

Here BrBrBr and NH3NH_3NH3​ are opposite to each other.

The trans form has sufficient symmetry and is optically inactive, so it gives only 1 stereoisomer.


  1. Total number of stereoisomers

Therefore, Total stereoisomers=2 (cis enantiomers)+1 (trans)=3\text{Total stereoisomers} = 2 \text{ (cis enantiomers)} + 1 \text{ (trans)} = 3Total stereoisomers=2 (cis enantiomers)+1 (trans)=3


  1. Final answer

3\boxed{3}3​


  1. Comparison with stored correct answer

Stored correct answer = 333

Our derived answer = 333

So the stored answer is correct.

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