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Coordination Compounds question

2021 · 31 Aug · Shift 2 · Q9
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Coordination Compounds question

2021 · 31 Aug · Shift 2 · Q9

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Spin only magnetic moment in BM of [Fe(CO)4(C2O4)]+[Fe(CO)_4(C_2O_4)]^+[Fe(CO)4​(C2​O4​)]+ is :
  1. A
    5.92
  2. B
    0
  3. C
    1
  4. D
    1.73
View written solutionFree

Correct answer: D

  1. Find oxidation state of Fe in [Fe(CO)4(C2O4)]+[Fe(CO)_4(C_2O_4)]^+[Fe(CO)4​(C2​O4​)]+

    • COCOCO is a neutral ligand.
    • Oxalate, C2O42−C_2O_4^{2-}C2​O42−​, has charge −2-2−2.
    • Let oxidation state of Fe be xxx.

    x+4(0)+(−2)=+1x + 4(0) + (-2) = +1x+4(0)+(−2)=+1 x=+3x = +3x=+3

    So, iron is Fe3+Fe^{3+}Fe3+.

  2. Find d-electron count

    Iron has atomic number 262626.

    Neutral Fe: [Ar]3d64s2[Ar]3d^64s^2[Ar]3d64s2

    For Fe3+Fe^{3+}Fe3+, remove 2 electrons from 4s4s4s and 1 from 3d3d3d:

    Fe3+:3d5Fe^{3+} : 3d^5Fe3+:3d5

  3. Determine the nature of ligands and pairing

    • COCOCO is a very strong field ligand.
    • Oxalate is weaker than COCOCO, but the presence of four COCOCO ligands makes the complex strongly field-stabilized.
    • Coordination number is 666 here: four COCOCO donors + bidentate oxalate.

    Thus, the complex is expected to be low spin octahedral.

  4. Electronic configuration in octahedral low-spin field

    For d5d^5d5 low spin:

    t2g5eg0t_{2g}^5 e_g^0t2g5​eg0​

    This gives one unpaired electron.

  5. Calculate spin-only magnetic moment

    Formula:

    μ=n(n+2) BM\mu = \sqrt{n(n+2)}\ \text{BM}μ=n(n+2)​ BM

    where n=n =n= number of unpaired electrons.

    Here, n=1n=1n=1:

    μ=1(1+2)=3≈1.73 BM\mu = \sqrt{1(1+2)} = \sqrt{3} \approx 1.73\ \text{BM}μ=1(1+2)​=3​≈1.73 BM

  6. Check options

    • A: 5.925.925.92 BM →\rightarrow→ corresponds to 5 unpaired electrons, incorrect
    • B: 000 BM →\rightarrow→ no unpaired electrons, incorrect
    • C: 111 BM →\rightarrow→ not the spin-only value
    • D: 1.731.731.73 BM →\rightarrow→ correct

Final Answer: 1.73 BM\boxed{1.73\ \text{BM}}1.73 BM​ (Option D)

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