JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Spin only magnetic moment in BM of is :
- A5.92
- B0
- C1
- D1.73
View written solutionFree
Correct answer: D
-
Find oxidation state of Fe in
- is a neutral ligand.
- Oxalate, , has charge .
- Let oxidation state of Fe be .
So, iron is .
-
Find d-electron count
Iron has atomic number .
Neutral Fe:
For , remove 2 electrons from and 1 from :
-
Determine the nature of ligands and pairing
- is a very strong field ligand.
- Oxalate is weaker than , but the presence of four ligands makes the complex strongly field-stabilized.
- Coordination number is here: four donors + bidentate oxalate.
Thus, the complex is expected to be low spin octahedral.
-
Electronic configuration in octahedral low-spin field
For low spin:
This gives one unpaired electron.
-
Calculate spin-only magnetic moment
Formula:
where number of unpaired electrons.
Here, :
-
Check options
- A: BM corresponds to 5 unpaired electrons, incorrect
- B: BM no unpaired electrons, incorrect
- C: BM not the spin-only value
- D: BM correct
Final Answer: (Option D)
More from Coordination Compounds
- Consider that a d6 metal ion () forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90 BM. The geometry and the crystal field stabilization energy of the complex is2020 · MCQ
- For octahedral Mn(II) and tetrahedral Ni(II) complexes, consider the following statements: (I) both the complexes can be high spin. (II) Ni(II) complex can very rarely be low spin. (III) with strong field ligands, Mn(II) complexes can be…2020 · MCQ
- The oxidation states of iron atoms in compounds (A), (B) and (C), respectively, are x, y and z. The sum of x, y and z is . (A) (B) (C)2020 · Numerical
- The one that is not expected to show isomerism is :2020 · MCQ
- Simplified absorption spectra of three complexes ((i), (ii) and (iii)) of ion are provided below; their max values are marked as A, B and C respectively. The correct match between the complexes and their max… Includes diagram2020 · MCQ
- The electronic spectrum of shows a single broad peak with a maximum at 20,300 cm-1 . The crystal field stabilization energy (CFSE) of the complex ion, in kJ mol-1, is :2020 · MCQ
- The complex that can show optical activity is :2020 · MCQ
- The d-electron configuration of and , respectively are :2020 · MCQ