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Coordination Compounds question

2021 · 27 Jul · Shift 2 · Q18
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Coordination Compounds question

2021 · 27 Jul · Shift 2 · Q18

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
3 moles of metal complex with formula Co(en)2Cl3Co(en)_2Cl_3Co(en)2​Cl3​ gives 3 moles of silver chloride on treatment with excess of silver nitrate. The secondary valency of Co in the complex is ‾\underline{\hspace{2cm}}​. (Round off to the nearest integer)
Numerical answer
View written solutionFree

Correct answer: 6

  1. Interpret the formula

    The given complex is written as: Co(en)2Cl3Co(en)_2Cl_3Co(en)2​Cl3​ where enenen = ethylenediamine, a bidentate ligand.

  2. Use the silver nitrate test

    We are told:

    • 333 moles of the complex give 333 moles of AgClAgClAgCl with excess AgNO3AgNO_3AgNO3​.

    Hence, 1 mole of the complex gives 1 mole of AgClAgClAgCl.

    Therefore, there is 1 chloride ion outside the coordination sphere.

    So the complex must actually be represented as: [Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl[Co(en)2​Cl2​]Cl

    because only the outer-sphere Cl−Cl^-Cl− reacts immediately with AgNO3AgNO_3AgNO3​ to form AgClAgClAgCl.

  3. Find the secondary valency

    Secondary valency = coordination number of the metal.

    In [Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl[Co(en)2​Cl2​]Cl:

    • each enenen is bidentate, so 222 ligands of enenen contribute: 2×2=42 \times 2 = 42×2=4
    • inside the coordination sphere, there are 222 coordinated Cl−Cl^-Cl− ligands, contributing: 222

    Therefore, total coordination number of Co is: 4+2=64 + 2 = 64+2=6

  4. Final answer

    The secondary valency of Co is: 6\boxed{6}6​

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