JEE MainChemistryCoordination CompoundsNumerical+4 / −1
3 moles of metal complex with formula gives 3 moles of silver chloride on treatment with excess of silver nitrate. The secondary valency of Co in the complex is . (Round off to the nearest integer)
Numerical answer
View written solutionFree
Correct answer: 6
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Interpret the formula
The given complex is written as: where = ethylenediamine, a bidentate ligand.
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Use the silver nitrate test
We are told:
- moles of the complex give moles of with excess .
Hence, 1 mole of the complex gives 1 mole of .
Therefore, there is 1 chloride ion outside the coordination sphere.
So the complex must actually be represented as:
because only the outer-sphere reacts immediately with to form .
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Find the secondary valency
Secondary valency = coordination number of the metal.
In :
- each is bidentate, so ligands of contribute:
- inside the coordination sphere, there are coordinated ligands, contributing:
Therefore, total coordination number of Co is:
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Final answer
The secondary valency of Co is:
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