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Coordination Compounds question

2021 · 18 Mar · Shift 1 · Q21
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  5. /2021 · 18 Mar · Shift 1 · Q21

Coordination Compounds question

2021 · 18 Mar · Shift 1 · Q21

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The total number of unpaired electrons present in the complex K3[Cr(oxalate)3]K_3[Cr(oxalate)_3]K3​[Cr(oxalate)3​] is ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 3

  1. Find the oxidation state of chromium in K_3[Cr( oxalate)_3].

    • The complex ion is [Cr(ox)3]3−[Cr(ox)_3]^{3-}[Cr(ox)3​]3− because there are 3K+3K^+3K+ outside.
    • Each oxalate ligand (ox)(ox)(ox) has charge −2-2−2.

    Let oxidation state of Cr be xxx: x+3(−2)=−3x + 3(-2) = -3x+3(−2)=−3 x−6=−3x - 6 = -3x−6=−3 x=+3x = +3x=+3

    So, chromium is Cr3+Cr^{3+}Cr3+.

  2. Write the electronic configuration of Cr3+Cr^{3+}Cr3+.

    • Atomic number of Cr = 24
    • Neutral Cr: [Ar]3d54s1[Ar]3d^5 4s^1[Ar]3d54s1
    • For Cr3+Cr^{3+}Cr3+, remove electrons first from 4s4s4s and then 3d3d3d: Cr3+=[Ar]3d3Cr^{3+} = [Ar]3d^3Cr3+=[Ar]3d3
  3. Nature of ligand and geometry.

    • Oxalate is a bidentate ligand.
    • Three oxalate ligands give coordination number 6, so the complex is octahedral.
  4. Distribution of d3d^3d3 electrons in octahedral field.

    In an octahedral crystal field: t2g<egt_{2g} < e_gt2g​<eg​

    For d3d^3d3 configuration, the electrons occupy: t2g3eg0t_{2g}^3 e_g^0t2g3​eg0​

    By Hund's rule, all three electrons remain unpaired in the three t2gt_{2g}t2g​ orbitals.

  5. Count unpaired electrons.

    Number of unpaired electrons = 333.

Therefore, the total number of unpaired electrons present in K3[Cr(oxalate)3]K_3[Cr(oxalate)_3]K3​[Cr(oxalate)3​] is: 3\boxed{3}3​

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