JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The total number of unpaired electrons present in the complex is .
Numerical answer
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Correct answer: 3
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Find the oxidation state of chromium in K_3[Cr(oxalate)_3].
- The complex ion is because there are outside.
- Each oxalate ligand has charge .
Let oxidation state of Cr be :
So, chromium is .
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Write the electronic configuration of .
- Atomic number of Cr = 24
- Neutral Cr:
- For , remove electrons first from and then :
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Nature of ligand and geometry.
- Oxalate is a bidentate ligand.
- Three oxalate ligands give coordination number 6, so the complex is octahedral.
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Distribution of electrons in octahedral field.
In an octahedral crystal field:
For configuration, the electrons occupy:
By Hund's rule, all three electrons remain unpaired in the three orbitals.
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Count unpaired electrons.
Number of unpaired electrons = .
Therefore, the total number of unpaired electrons present in is:
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