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Coordination Compounds question

2021 · 20 Jul · Shift 1 · Q15
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Coordination Compounds question

2021 · 20 Jul · Shift 1 · Q15

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The spin-only magnetic moment value for the complex [Co(CN)6]4−[Co(CN)_6]^{4-}[Co(CN)6​]4− is ‾\underline{\hspace{2cm}}​ BM. [At. no. of Co = 27]
Numerical answer
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Correct answer: 2

  1. Find the oxidation state of Co in [Co(CN)6]4−[Co(CN)_6]^{4-}[Co(CN)6​]4−.

    Let the oxidation state of Co be xxx.

    Each CN−CN^-CN− ligand has charge −1-1−1, so: x+6(−1)=−4x + 6(-1) = -4x+6(−1)=−4 x−6=−4x - 6 = -4x−6=−4 x=+2x = +2x=+2

    So, the metal ion is Co2+Co^{2+}Co2+.

  2. Write the electronic configuration of Co2+Co^{2+}Co2+.

    Atomic number of Co = 27.

    Neutral Co: Co:[Ar] 3d74s2Co: [Ar] \, 3d^7 4s^2Co:[Ar]3d74s2

    For Co2+Co^{2+}Co2+, remove two electrons from 4s4s4s first: Co2+:[Ar] 3d7Co^{2+}: [Ar] \, 3d^7Co2+:[Ar]3d7

  3. Determine the nature of the ligand.

    CN−CN^-CN− is a strong field ligand. Hence, in an octahedral complex it causes pairing of electrons.

  4. Distribute electrons in octahedral crystal field.

    For a strong field octahedral d7d^7d7 configuration: t2g6eg1t_{2g}^6 e_g^1t2g6​eg1​

    Number of unpaired electrons, n=1n = 1n=1.

  5. Calculate the spin-only magnetic moment.

    Formula: μ=n(n+2) BM\mu = \sqrt{n(n+2)} \, \text{BM}μ=n(n+2)​BM

    Putting n=1n=1n=1: μ=1(1+2)=3≈1.73 BM\mu = \sqrt{1(1+2)} = \sqrt{3} \approx 1.73 \, \text{BM}μ=1(1+2)​=3​≈1.73BM

  6. Integer answer.

    Since the question asks for an integer value, the magnetic moment is approximately: 1.73≈2 BM1.73 \approx 2 \text{ BM}1.73≈2 BM

Final Answer: 222

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