JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The spin-only magnetic moment value for the complex is BM. [At. no. of Co = 27]
Numerical answer
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Correct answer: 2
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Find the oxidation state of Co in .
Let the oxidation state of Co be .
Each ligand has charge , so:
So, the metal ion is .
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Write the electronic configuration of .
Atomic number of Co = 27.
Neutral Co:
For , remove two electrons from first:
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Determine the nature of the ligand.
is a strong field ligand. Hence, in an octahedral complex it causes pairing of electrons.
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Distribute electrons in octahedral crystal field.
For a strong field octahedral configuration:
Number of unpaired electrons, .
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Calculate the spin-only magnetic moment.
Formula:
Putting :
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Integer answer.
Since the question asks for an integer value, the magnetic moment is approximately:
Final Answer:
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