JEE MainChemistryCoordination CompoundsMCQ+4 / −1
The correct order of intensity of colors of the compounds is :
- A
- B
- C
- D
View written solutionFree
Correct answer: C
- Identify the complexes and their geometries / electronic situations
All three complexes contain , so the metal ion is .
- : octahedral, weak-field ligand
- : tetrahedral, weak-field ligand
- : square planar, strong-field ligand
- Color intensity depends on allowedness of - transitions
The intensity of color is related to how strongly the complex absorbs light. For coordination compounds, this depends largely on whether the electronic transition is Laporte allowed or forbidden.
- In octahedral complexes with a center of symmetry, - transitions are Laporte forbidden weak color.
- In tetrahedral complexes, there is no center of symmetry, so - transitions are more allowed stronger color.
- In square planar complexes, especially with strong-field ligand , the splitting is large and the principal transitions are comparatively less intense in the visible region; such complexes are generally less intensely colored than tetrahedral .
- Compare the three complexes
(i)
- Tetrahedral complex
- No inversion center
- - transitions relatively more intense
So this should have the highest color intensity.
(ii)
- Octahedral complex
- Has inversion center
- - transitions Laporte forbidden
So its color intensity is less than tetrahedral .
(iii)
- Square planar, strong-field complex
- For nickel, this is low-spin and often shows comparatively weak visible absorption for the relevant transition pattern.
- Hence its observed color intensity is lower than the other two.
- Therefore, the order of intensity of colors is
- Match with the options
This corresponds to Option C.
- Comparison with stored correct answer
Stored correct answer = C
Our derived answer = C
Hence, they agree.
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