JEE MainChemistryCoordination CompoundsNumerical+4 / −1
An aqueous solution of was heated with excess sodium cyanide in presence of strong oxidizing agent to form . The total change in number of unpaired electrons on metal centre is .
Numerical answer
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Correct answer: 2
- Find oxidation state and electronic configuration of metal in the reactant
In aqueous solution, contains .
Nickel atom:
So,
For free , the number of unpaired electrons in is 2.
- Determine oxidation state of Ni in the product
Given complex:
Let oxidation state of Ni be .
Since each has charge ,
So metal centre is .
Now electronic configuration:
- Nature of ligand and spin state
is a strong field ligand. Hence in octahedral complex , electrons pair up to give a low-spin arrangement.
For octahedral low-spin :
All electrons are paired.
So number of unpaired electrons in is 0.
- Calculate total change in number of unpaired electrons
Initial unpaired electrons on metal centre =
Final unpaired electrons on metal centre =
Therefore,
- Final answer
The total change in number of unpaired electrons is:
- Comparison with stored correct answer
Stored correct answer =
This matches the derived answer.
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