JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Spin only magnetic moment of an octahedral complex of in the presence of a strong field ligand in BM is :
- A4.89
- B2.82
- C0
- D3.46
View written solutionFree
Correct answer: C
-
Determine the electronic configuration of
Iron has atomic number .
Neutral iron:
For , two electrons are removed from the orbital first:
-
Consider octahedral crystal field with strong field ligand
In an octahedral field, the -orbitals split into:
- lower energy set
- higher energy set
Since the ligand is strong field, electrons pair up in the lower-energy orbitals before occupying .
So for low-spin octahedral configuration:
-
Count unpaired electrons
In , all six electrons are paired.
Therefore, number of unpaired electrons:
-
Use spin-only magnetic moment formula
Substituting :
-
Match with options
The correct option is:
-
Compare with stored correct answer
Stored correct answer is C, which matches the derived answer.
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