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Coordination Compounds question

2021 · 20 Jul · Shift 2 · Q7
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  5. /2021 · 20 Jul · Shift 2 · Q7

Coordination Compounds question

2021 · 20 Jul · Shift 2 · Q7

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Spin only magnetic moment of an octahedral complex of Fe2+Fe^{2+}Fe2+ in the presence of a strong field ligand in BM is :
  1. A
    4.89
  2. B
    2.82
  3. C
    0
  4. D
    3.46
View written solutionFree

Correct answer: C

  1. Determine the electronic configuration of Fe2+Fe^{2+}Fe2+

    Iron has atomic number 262626.

    Neutral iron: Fe:[Ar] 3d64s2Fe: [Ar] \, 3d^6 4s^2Fe:[Ar]3d64s2

    For Fe2+Fe^{2+}Fe2+, two electrons are removed from the 4s4s4s orbital first: Fe2+:[Ar] 3d6Fe^{2+}: [Ar] \, 3d^6Fe2+:[Ar]3d6

  2. Consider octahedral crystal field with strong field ligand

    In an octahedral field, the ddd-orbitals split into:

    • lower energy t2gt_{2g}t2g​ set
    • higher energy ege_geg​ set

    Since the ligand is strong field, electrons pair up in the lower-energy t2gt_{2g}t2g​ orbitals before occupying ege_geg​.

    So for d6d^6d6 low-spin octahedral configuration: t2g6eg0t_{2g}^6 e_g^0t2g6​eg0​

  3. Count unpaired electrons

    In t2g6eg0t_{2g}^6 e_g^0t2g6​eg0​, all six electrons are paired.

    Therefore, number of unpaired electrons: n=0n = 0n=0

  4. Use spin-only magnetic moment formula

    μ=n(n+2) BM\mu = \sqrt{n(n+2)} \text{ BM}μ=n(n+2)​ BM

    Substituting n=0n=0n=0: μ=0(0+2)=0 BM\mu = \sqrt{0(0+2)} = 0 \text{ BM}μ=0(0+2)​=0 BM

  5. Match with options

    The correct option is: C: 0\boxed{\text{C: } 0}C: 0​

  6. Compare with stored correct answer

    Stored correct answer is C, which matches the derived answer.

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