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Coordination Compounds question

2021 · 16 Mar · Shift 1 · Q14
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Coordination Compounds question

2021 · 16 Mar · Shift 1 · Q14

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The equivalents of ethylene diamine required to replace the neutral ligands from the coordination sphere of the trans-complex of CoCl3CoCl_3CoCl3​ . 4NH3NH_3NH3​ is ‾\underline{\hspace{2cm}}​. (Round off to the Nearest Integer).
Numerical answer
View written solutionFree

Correct answer: 2

  1. Identify the complex

    The given compound is: CoCl3⋅4NH3CoCl_3\cdot 4NH_3CoCl3​⋅4NH3​

    Since the question mentions the trans-complex, this corresponds to the coordination compound: trans−[Co(NH3)4Cl2]Cltrans-[Co(NH_3)_4Cl_2]Cltrans−[Co(NH3​)4​Cl2​]Cl

    Here:

    • Inside the coordination sphere: 4NH34NH_34NH3​ and 2Cl−2Cl^-2Cl−
    • Outside the coordination sphere: 1Cl−1Cl^-1Cl−
  2. Find the neutral ligands in the coordination sphere

    The neutral ligands present inside the coordination sphere are ammonia molecules: 4NH34NH_34NH3​

  3. Understand the replacing ligand

    Ethylenediamine (en) is a bidentate neutral ligand, so:

    • 1 molecule of en occupies 2 coordination sites
  4. Replace all neutral ligands

    We need to replace all 444 ammonia ligands by en.

    Since: 1 en≡2 NH31\,en \equiv 2\,NH_31en≡2NH3​

    Therefore, the number of en molecules required is: 42=2\frac{4}{2} = 224​=2

  5. Nearest integer

    The value is already an integer: 222

Final Answer

2\boxed{2}2​

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