JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The equivalents of ethylene diamine required to replace the neutral ligands from the coordination sphere of the trans-complex of . 4 is . (Round off to the Nearest Integer).
Numerical answer
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Correct answer: 2
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Identify the complex
The given compound is:
Since the question mentions the trans-complex, this corresponds to the coordination compound:
Here:
- Inside the coordination sphere: and
- Outside the coordination sphere:
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Find the neutral ligands in the coordination sphere
The neutral ligands present inside the coordination sphere are ammonia molecules:
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Understand the replacing ligand
Ethylenediamine (en) is a bidentate neutral ligand, so:
- 1 molecule of en occupies 2 coordination sites
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Replace all neutral ligands
We need to replace all ammonia ligands by en.
Since:
Therefore, the number of en molecules required is:
-
Nearest integer
The value is already an integer:
Final Answer
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