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Redox Reactions question

2011 · Shift 2 · Q15
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Redox Reactions question

2011 · Shift 2 · Q15

JEE AdvancedChemistryRedox ReactionsMultiple correct+4 / −2
Reduction of the metal centre in aqueous permanganate ion involves
  1. A
    3 electrons in neutral medium.
  2. B
    5 electrons in neutral medium.
  3. C
    3 electrons in alkaline medium.
  4. D
    5 electrons in acidic medium.
View written solutionFree

Correct answer: A, C, D

To determine the number of electrons involved in the reduction of the permanganate ion (MnO4−MnO_4^-MnO4−​), we need to analyze its behavior in different media (acidic, neutral, and alkaline). First, we find the oxidation state of the metal center, Manganese (Mn), in MnO4−MnO_4^-MnO4−​.

  1. Oxidation state of Mn in MnO4−MnO_4^-MnO4−​: Let the oxidation state of Mn be xxx. The oxidation state of each oxygen atom is -2. The overall charge of the ion is -1. x+4(−2)=−1x + 4(-2) = -1x+4(−2)=−1 x−8=−1x - 8 = -1x−8=−1 x=+7x = +7x=+7 So, Mn is in the +7 oxidation state.

  2. Reduction in Acidic Medium: In a strongly acidic medium, the permanganate ion (MnO4−MnO_4^-MnO4−​) is reduced to the manganous ion (Mn2+Mn^{2+}Mn2+).

    • Initial oxidation state of Mn = +7
    • Final oxidation state of Mn in Mn2+Mn^{2+}Mn2+ = +2
    • Change in oxidation state = 7−2=57 - 2 = 57−2=5
    • This means the reduction involves the gain of 5 electrons. The balanced half-reaction is: MnO4−+8H++5e−→Mn2++4H2OMnO_4^- + 8H^+ + 5e^- \rightarrow Mn^{2+} + 4H_2OMnO4−​+8H++5e−→Mn2++4H2​O Therefore, the reduction involves 5 electrons in an acidic medium.
    • This confirms that Option D is correct.
  3. Reduction in Neutral or Weakly Alkaline Medium: In a neutral or weakly alkaline medium, the permanganate ion (MnO4−MnO_4^-MnO4−​) is reduced to manganese dioxide (MnO2MnO_2MnO2​).

    • Initial oxidation state of Mn = +7
    • Final oxidation state of Mn in MnO2MnO_2MnO2​ = +4
    • Change in oxidation state = 7−4=37 - 4 = 37−4=3
    • This means the reduction involves the gain of 3 electrons. The balanced half-reaction is: MnO4−+2H2O+3e−→MnO2+4OH−MnO_4^- + 2H_2O + 3e^- \rightarrow MnO_2 + 4OH^-MnO4−​+2H2​O+3e−→MnO2​+4OH− This reaction is characteristic of both neutral and weakly alkaline conditions.
    • Therefore, the reduction involves 3 electrons in a neutral medium. Option A is correct.
    • Option B (5 electrons in neutral medium) is incorrect.
    • The reduction also involves 3 electrons in an alkaline (specifically, weakly alkaline) medium. Option C is correct.
  4. Reduction in Strongly Alkaline Medium: In a strongly alkaline medium, permanganate (MnO4−MnO_4^-MnO4−​) is reduced to manganate (MnO42−MnO_4^{2-}MnO42−​).

    • Initial oxidation state of Mn = +7
    • Final oxidation state of Mn in MnO42−MnO_4^{2-}MnO42−​ = +6
    • Change in oxidation state = 7−6=17 - 6 = 17−6=1
    • This involves a 1-electron gain. This case is not presented in the options, but it's important to distinguish it from the weakly alkaline case.

Conclusion: Based on the analysis:

  • Option A: Correct. Reduction in neutral medium involves 3 electrons (to MnO2MnO_2MnO2​).
  • Option B: Incorrect.
  • Option C: Correct. Reduction in weakly alkaline medium involves 3 electrons (to MnO2MnO_2MnO2​).
  • Option D: Correct. Reduction in acidic medium involves 5 electrons (to Mn2+Mn^{2+}Mn2+).
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