- A3 electrons in neutral medium.
- B5 electrons in neutral medium.
- C3 electrons in alkaline medium.
- D5 electrons in acidic medium.
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Correct answer: A, C, D
To determine the number of electrons involved in the reduction of the permanganate ion (), we need to analyze its behavior in different media (acidic, neutral, and alkaline). First, we find the oxidation state of the metal center, Manganese (Mn), in .
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Oxidation state of Mn in : Let the oxidation state of Mn be . The oxidation state of each oxygen atom is -2. The overall charge of the ion is -1. So, Mn is in the +7 oxidation state.
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Reduction in Acidic Medium: In a strongly acidic medium, the permanganate ion () is reduced to the manganous ion ().
- Initial oxidation state of Mn = +7
- Final oxidation state of Mn in = +2
- Change in oxidation state =
- This means the reduction involves the gain of 5 electrons. The balanced half-reaction is: Therefore, the reduction involves 5 electrons in an acidic medium.
- This confirms that Option D is correct.
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Reduction in Neutral or Weakly Alkaline Medium: In a neutral or weakly alkaline medium, the permanganate ion () is reduced to manganese dioxide ().
- Initial oxidation state of Mn = +7
- Final oxidation state of Mn in = +4
- Change in oxidation state =
- This means the reduction involves the gain of 3 electrons. The balanced half-reaction is: This reaction is characteristic of both neutral and weakly alkaline conditions.
- Therefore, the reduction involves 3 electrons in a neutral medium. Option A is correct.
- Option B (5 electrons in neutral medium) is incorrect.
- The reduction also involves 3 electrons in an alkaline (specifically, weakly alkaline) medium. Option C is correct.
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Reduction in Strongly Alkaline Medium: In a strongly alkaline medium, permanganate () is reduced to manganate ().
- Initial oxidation state of Mn = +7
- Final oxidation state of Mn in = +6
- Change in oxidation state =
- This involves a 1-electron gain. This case is not presented in the options, but it's important to distinguish it from the weakly alkaline case.
Conclusion: Based on the analysis:
- Option A: Correct. Reduction in neutral medium involves 3 electrons (to ).
- Option B: Incorrect.
- Option C: Correct. Reduction in weakly alkaline medium involves 3 electrons (to ).
- Option D: Correct. Reduction in acidic medium involves 5 electrons (to ).
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