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Redox Reactions question

2025 · Shift 1 · Q3
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Redox Reactions question

2025 · Shift 1 · Q3

JEE AdvancedChemistryRedox ReactionsMCQ+3 / −1
One of the products formed from the reaction of permanganate ion with iodide ion in neutral aqueous medium is
  1. A
    I2I_2I2​
  2. B
    IO3−{}_3^-3−​
  3. C
    IO4−{}_4^-4−​
  4. D
    IO2−{}_2^-2−​
View written solutionFree

Correct answer: B

Step-by-step Solution:

  1. Identify Reactants and Reaction Conditions: The reaction involves permanganate ion (MnO4−MnO_4^-MnO4−​) and iodide ion (I−I^-I−) in a neutral aqueous medium.

  2. Identify Oxidizing and Reducing Agents:

    • Permanganate ion (MnO4−MnO_4^-MnO4−​) is a strong oxidizing agent. The oxidation state of manganese (Mn) is +7.
    • Iodide ion (I−I^-I−) is a reducing agent. The oxidation state of iodine (I) is -1. A redox reaction will occur between these two ions.
  3. Determine the Half-Reactions in a Neutral Medium: The products of a redox reaction involving permanganate depend on the pH of the medium.

    • Reduction of Permanganate (MnO4−MnO_4^-MnO4−​): In a neutral or weakly alkaline aqueous medium, permanganate ion is reduced to manganese dioxide (MnO2MnO_2MnO2​), where the oxidation state of Mn is +4. The unbalanced reduction half-reaction is: MnO4−→MnO2MnO_4^- \to MnO_2MnO4−​→MnO2​ To balance this half-reaction: a. The oxidation state of Mn changes from +7 to +4, a gain of 3 electrons. MnO4−+3e−→MnO2MnO_4^- + 3e^- \to MnO_2MnO4−​+3e−→MnO2​ b. Balance the oxygen atoms by adding water (H2OH_2OH2​O) to the right side. MnO4−+3e−→MnO2+2H2OMnO_4^- + 3e^- \to MnO_2 + 2H_2OMnO4−​+3e−→MnO2​+2H2​O c. Balance the hydrogen atoms by adding H+^++ to the left side. MnO4−+4H++3e−→MnO2+2H2OMnO_4^- + 4H^+ + 3e^- \to MnO_2 + 2H_2OMnO4−​+4H++3e−→MnO2​+2H2​O d. Since the reaction is in a neutral medium, we neutralize the H+^++ ions by adding an equal number of OH−^-− ions to both sides. MnO4−+4H++4OH−+3e−→MnO2+2H2O+4OH−MnO_4^- + 4H^+ + 4OH^- + 3e^- \to MnO_2 + 2H_2O + 4OH^-MnO4−​+4H++4OH−+3e−→MnO2​+2H2​O+4OH− This simplifies to: MnO4−+4H2O+3e−→MnO2+2H2O+4OH−MnO_4^- + 4H_2O + 3e^- \to MnO_2 + 2H_2O + 4OH^-MnO4−​+4H2​O+3e−→MnO2​+2H2​O+4OH− e. Canceling water molecules from both sides gives the final balanced reduction half-reaction: MnO4−+2H2O+3e−→MnO2+4OH−MnO_4^- + 2H_2O + 3e^- \to MnO_2 + 4OH^-MnO4−​+2H2​O+3e−→MnO2​+4OH−

    • Oxidation of Iodide (I−I^-I−): In a neutral or alkaline medium, the strong oxidizing agent permanganate oxidizes iodide ion (I−I^-I−) to iodate ion (IO3−IO_3^-IO3−​), where the oxidation state of I is +5. The unbalanced oxidation half-reaction is: I−→IO3−I^- \to IO_3^-I−→IO3−​ To balance this half-reaction: a. The oxidation state of I changes from -1 to +5, a loss of 6 electrons. I−→IO3−+6e−I^- \to IO_3^- + 6e^-I−→IO3−​+6e− b. Balance the oxygen atoms by adding OH−^-− ions to the left side (since the reduction half-reaction produces OH−^-−, the medium will become basic). I−+6OH−→IO3−+6e−I^- + 6OH^- \to IO_3^- + 6e^-I−+6OH−→IO3−​+6e− c. Balance the hydrogen atoms by adding water (H2OH_2OH2​O) to the right side. I−+6OH−→IO3−+3H2O+6e−I^- + 6OH^- \to IO_3^- + 3H_2O + 6e^-I−+6OH−→IO3−​+3H2​O+6e− This is the balanced oxidation half-reaction.

  4. Combine the Half-Reactions: To get the overall balanced equation, the number of electrons lost in oxidation must equal the number of electrons gained in reduction.

    • Reduction: MnO4−+2H2O+3e−→MnO2+4OH−MnO_4^- + 2H_2O + 3e^- \to MnO_2 + 4OH^-MnO4−​+2H2​O+3e−→MnO2​+4OH−
    • Oxidation: I−+6OH−→IO3−+3H2O+6e−I^- + 6OH^- \to IO_3^- + 3H_2O + 6e^-I−+6OH−→IO3−​+3H2​O+6e−

    Multiply the reduction half-reaction by 2 to balance the electrons (6 electrons in both). 2(MnO4−+2H2O+3e−→MnO2+4OH−)  ⟹  2MnO4−+4H2O+6e−→2MnO2+8OH−2(MnO_4^- + 2H_2O + 3e^- \to MnO_2 + 4OH^-) \implies 2MnO_4^- + 4H_2O + 6e^- \to 2MnO_2 + 8OH^-2(MnO4−​+2H2​O+3e−→MnO2​+4OH−)⟹2MnO4−​+4H2​O+6e−→2MnO2​+8OH−

    Now add the two balanced half-reactions: (2MnO4−+4H2O+6e−)+(I−+6OH−)→(2MnO2+8OH−)+(IO3−+3H2O+6e−)(2MnO_4^- + 4H_2O + 6e^-) + (I^- + 6OH^-) \to (2MnO_2 + 8OH^-) + (IO_3^- + 3H_2O + 6e^-)(2MnO4−​+4H2​O+6e−)+(I−+6OH−)→(2MnO2​+8OH−)+(IO3−​+3H2​O+6e−)

  5. Simplify the Overall Equation: Cancel the electrons (6e−6e^-6e−) and simplify the water (H2OH_2OH2​O) and hydroxide (OH−OH^-OH−) ions from both sides. 2MnO4−+4H2O+I−+6OH−→2MnO2+8OH−+IO3−+3H2O2MnO_4^- + 4H_2O + I^- + 6OH^- \to 2MnO_2 + 8OH^- + IO_3^- + 3H_2O2MnO4−​+4H2​O+I−+6OH−→2MnO2​+8OH−+IO3−​+3H2​O 2MnO4−+H2O+I−→2MnO2+2OH−+IO3−2MnO_4^- + H_2O + I^- \to 2MnO_2 + 2OH^- + IO_3^-2MnO4−​+H2​O+I−→2MnO2​+2OH−+IO3−​

  6. Identify the Products and Compare with Options: The final products of the reaction are manganese dioxide (MnO2MnO_2MnO2​), hydroxide ions (OH−OH^-OH−), and iodate ion (IO3−IO_3^-IO3−​). Looking at the given options: A: I2I_2I2​ B: IO3−IO_3^-IO3−​ C: IO4−IO_4^-IO4−​ D: IO2−IO_2^-IO2−​

    One of the products is IO3−IO_3^-IO3−​, which corresponds to option B.

Conclusion

In a neutral aqueous medium, permanganate ion oxidizes iodide ion to iodate ion (IO3−IO_3^-IO3−​). Therefore, IO3−IO_3^-IO3−​ is one of the products formed. The correct option is B.

Next

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