- A
- BIO
- CIO
- DIO
View written solutionFree
Correct answer: B
Step-by-step Solution:
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Identify Reactants and Reaction Conditions: The reaction involves permanganate ion () and iodide ion () in a neutral aqueous medium.
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Identify Oxidizing and Reducing Agents:
- Permanganate ion () is a strong oxidizing agent. The oxidation state of manganese (Mn) is +7.
- Iodide ion () is a reducing agent. The oxidation state of iodine (I) is -1. A redox reaction will occur between these two ions.
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Determine the Half-Reactions in a Neutral Medium: The products of a redox reaction involving permanganate depend on the pH of the medium.
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Reduction of Permanganate (): In a neutral or weakly alkaline aqueous medium, permanganate ion is reduced to manganese dioxide (), where the oxidation state of Mn is +4. The unbalanced reduction half-reaction is: To balance this half-reaction: a. The oxidation state of Mn changes from +7 to +4, a gain of 3 electrons. b. Balance the oxygen atoms by adding water () to the right side. c. Balance the hydrogen atoms by adding H to the left side. d. Since the reaction is in a neutral medium, we neutralize the H ions by adding an equal number of OH ions to both sides. This simplifies to: e. Canceling water molecules from both sides gives the final balanced reduction half-reaction:
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Oxidation of Iodide (): In a neutral or alkaline medium, the strong oxidizing agent permanganate oxidizes iodide ion () to iodate ion (), where the oxidation state of I is +5. The unbalanced oxidation half-reaction is: To balance this half-reaction: a. The oxidation state of I changes from -1 to +5, a loss of 6 electrons. b. Balance the oxygen atoms by adding OH ions to the left side (since the reduction half-reaction produces OH, the medium will become basic). c. Balance the hydrogen atoms by adding water () to the right side. This is the balanced oxidation half-reaction.
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Combine the Half-Reactions: To get the overall balanced equation, the number of electrons lost in oxidation must equal the number of electrons gained in reduction.
- Reduction:
- Oxidation:
Multiply the reduction half-reaction by 2 to balance the electrons (6 electrons in both).
Now add the two balanced half-reactions:
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Simplify the Overall Equation: Cancel the electrons () and simplify the water () and hydroxide () ions from both sides.
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Identify the Products and Compare with Options: The final products of the reaction are manganese dioxide (), hydroxide ions (), and iodate ion (). Looking at the given options: A: B: C: D:
One of the products is , which corresponds to option B.
Conclusion
In a neutral aqueous medium, permanganate ion oxidizes iodide ion to iodate ion (). Therefore, is one of the products formed. The correct option is B.
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