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Redox Reactions question

2021 · Shift 2 · Q12
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Redox Reactions question

2021 · Shift 2 · Q12

JEE AdvancedChemistryRedox ReactionsNumerical+2 / −1
A sample (5.6 g) containing iron is completely dissolved in cold dilute HClHClHCl to prepare a 250 mL of solution. Titration of 25.0 mL of this solution requires 12.5 mL of 0.03 M KMnO4KMnO_4KMnO4​ solution to reach the end point. Number of moles of Fe2+Fe^{2+}Fe2+ present in 250 mL solution is x ×\times× 10 −-− 2 (consider complete dissolution of FeCl2FeCl_2FeCl2​). The amount of iron present in the sample is y% by weight. (Assume : KMnO4KMnO_4KMnO4​ reacts only with Fe2+Fe^{2+}Fe2+ in the solution Use : Molar mass of iron as 56 g mol −-− 1) The value of y is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 18.75

  1. Reaction involved in acidic medium

    KMnO4KMnO_4KMnO4​ oxidizes Fe2+Fe^{2+}Fe2+ to Fe3+Fe^{3+}Fe3+:

    MnO4−+5Fe2++8H+→Mn2++5Fe3++4H2OMnO_4^- + 5Fe^{2+} + 8H^+ \rightarrow Mn^{2+} + 5Fe^{3+} + 4H_2OMnO4−​+5Fe2++8H+→Mn2++5Fe3++4H2​O

    So,

    1 mole KMnO4 reacts with 5 moles Fe2+1 \text{ mole } KMnO_4 \text{ reacts with } 5 \text{ moles } Fe^{2+}1 mole KMnO4​ reacts with 5 moles Fe2+

  2. Moles of KMnO4KMnO_4KMnO4​ used for 25.0 mL aliquot

    Volume of KMnO4=12.5 mL=0.0125 LKMnO_4 = 12.5 \text{ mL} = 0.0125 \text{ L}KMnO4​=12.5 mL=0.0125 L

    Molarity of KMnO4=0.03 MKMnO_4 = 0.03 \text{ M}KMnO4​=0.03 M

    n(KMnO4)=M×V=0.03×0.0125=3.75×10−4 moln(KMnO_4) = M \times V = 0.03 \times 0.0125 = 3.75 \times 10^{-4} \text{ mol}n(KMnO4​)=M×V=0.03×0.0125=3.75×10−4 mol

  3. Moles of Fe2+Fe^{2+}Fe2+ in 25.0 mL solution

    Using the stoichiometric ratio 1:51:51:5,

    n(Fe2+)=5×3.75×10−4=1.875×10−3 moln(Fe^{2+}) = 5 \times 3.75 \times 10^{-4} = 1.875 \times 10^{-3} \text{ mol}n(Fe2+)=5×3.75×10−4=1.875×10−3 mol

  4. Moles of Fe2+Fe^{2+}Fe2+ in total 250 mL solution

    Total volume is 10 times the aliquot volume:

    n(Fe2+)250mL=10×1.875×10−3=1.875×10−2 moln(Fe^{2+})_{250 mL} = 10 \times 1.875 \times 10^{-3} = 1.875 \times 10^{-2} \text{ mol}n(Fe2+)250mL​=10×1.875×10−3=1.875×10−2 mol

    Thus,

    x=1.875x = 1.875x=1.875

  5. Mass of iron in the sample

    Since iron dissolves as FeCl2FeCl_2FeCl2​, moles of iron === moles of Fe2+Fe^{2+}Fe2+:

    n(Fe)=1.875×10−2 moln(Fe) = 1.875 \times 10^{-2} \text{ mol}n(Fe)=1.875×10−2 mol

    Mass of iron:

    m(Fe)=n×M=1.875×10−2×56=1.05 gm(Fe) = n \times M = 1.875 \times 10^{-2} \times 56 = 1.05 \text{ g}m(Fe)=n×M=1.875×10−2×56=1.05 g

  6. Percentage by mass of iron in 5.6 g sample

    y=1.055.6×100=18.75%y = \frac{1.05}{5.6} \times 100 = 18.75\%y=5.61.05​×100=18.75%

  7. Final answer

    y=18.75\boxed{y = 18.75}y=18.75​

The derived answer matches the stored correct answer.

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