JEE AdvancedChemistryRedox ReactionsNumerical+2 / −1
A sample (5.6 g) containing iron is completely dissolved in cold dilute to prepare a 250 mL of solution. Titration of 25.0 mL of this solution requires 12.5 mL of 0.03 M solution to reach the end point. Number of moles of present in 250 mL solution is x 10 2 (consider complete dissolution of ). The amount of iron present in the sample is y% by weight. (Assume : reacts only with in the solution Use : Molar mass of iron as 56 g mol 1) The value of y is .
Numerical answer
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Correct answer: 18.75
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Reaction involved in acidic medium
oxidizes to :
So,
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Moles of used for 25.0 mL aliquot
Volume of
Molarity of
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Moles of in 25.0 mL solution
Using the stoichiometric ratio ,
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Moles of in total 250 mL solution
Total volume is 10 times the aliquot volume:
Thus,
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Mass of iron in the sample
Since iron dissolves as , moles of iron moles of :
Mass of iron:
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Percentage by mass of iron in 5.6 g sample
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Final answer
The derived answer matches the stored correct answer.
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