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Redox Reactions question

2020 · Shift 2 · Q10
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Redox Reactions question

2020 · Shift 2 · Q10

JEE AdvancedChemistryRedox ReactionsMultiple correct+4 / −2
Choose the correct statement(s) among the following :
  1. A
    SnCl2SnCl_2SnCl2​ . 2H2OH_2OH2​O is a reducing agent.
  2. B
    SnO2SnO_2SnO2​ reacts with KOHKOHKOH to form K2[Sn(OH)6]K_2[Sn(OH)_6]K2​[Sn(OH)6​].
  3. C
    A solution of PbCl2PbCl_2PbCl2​ in HClHClHCl contains Pb2+Pb^{2+}Pb2+ and Cl−Cl^-Cl− ions.
  4. D
    The reaction of Pb3O4Pb_3O_4Pb3​O4​ with hot dilute nitric acid to give PbO2PbO_2PbO2​ is a redox reaction.
View written solutionFree

Correct answer: A, B

  1. Evaluate option A: SnCl2⋅2H2OSnCl_2\cdot 2H_2OSnCl2​⋅2H2​O is stannous chloride dihydrate, where tin is in the +2+2+2 oxidation state.

    • Sn2+Sn^{2+}Sn2+ is easily oxidized to Sn4+Sn^{4+}Sn4+.
    • Therefore, it acts as a reducing agent.

    Hence, A is correct.

  2. Evaluate option B: SnO2SnO_2SnO2​ is amphoteric and reacts with strong bases like KOHKOHKOH.

    The reaction is: SnO2+2KOH+2H2O→K2[Sn(OH)6]SnO_2 + 2KOH + 2H_2O \rightarrow K_2[Sn(OH)_6]SnO2​+2KOH+2H2​O→K2​[Sn(OH)6​]

    So SnO2SnO_2SnO2​ does react with KOHKOHKOH to form hexahydroxostannate(IV), K2[Sn(OH)6]K_2[Sn(OH)_6]K2​[Sn(OH)6​].

    Hence, B is correct.

  3. Evaluate option C: A solution of PbCl2PbCl_2PbCl2​ in excess HClHClHCl does not contain only Pb2+Pb^{2+}Pb2+ and Cl−Cl^-Cl− ions.

    • In chloride-rich medium, Pb2+Pb^{2+}Pb2+ forms complex chloro-species such as [PbCl3]−[PbCl_3]^-[PbCl3​]− and [PbCl4]2−[PbCl_4]^{2-}[PbCl4​]2−.
    • Therefore, the statement is incomplete/incorrect.

    Hence, C is incorrect.

  4. Evaluate option D: Consider the reaction of Pb3O4Pb_3O_4Pb3​O4​ with hot dilute HNO3HNO_3HNO3​.

    • Pb3O4Pb_3O_4Pb3​O4​ can be written as 2PbO⋅PbO22PbO\cdot PbO_22PbO⋅PbO2​, containing lead in both +2+2+2 and +4+4+4 states.
    • On treatment with hot dilute nitric acid: Pb3O4+4HNO3→2Pb(NO3)2+PbO2+2H2OPb_3O_4 + 4HNO_3 \rightarrow 2Pb(NO_3)_2 + PbO_2 + 2H_2OPb3​O4​+4HNO3​→2Pb(NO3​)2​+PbO2​+2H2​O
    • Here, Pb2+Pb^{2+}Pb2+ remains Pb2+Pb^{2+}Pb2+ and Pb4+Pb^{4+}Pb4+ remains Pb4+Pb^{4+}Pb4+.
    • No oxidation number changes occur.

    Therefore, this is not a redox reaction.

    Hence, D is incorrect.

  5. Final answer: The correct statements are: A, B\boxed{A,\ B}A, B​

  6. Comparison with stored correct answer: Stored correct answer is A, B, which matches the derived answer.

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