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Redox Reactions question

2016 · Shift 1 · Q11
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  5. /2016 · Shift 1 · Q11

Redox Reactions question

2016 · Shift 1 · Q11

JEE AdvancedChemistryRedox ReactionsNumerical+3 / −1
In neutral or faintly alkaline solution, 8 moles of permanganate anion quantitative oxidise thiosulphate anions to produce X moles of a sulphur containing product. The magnitude of X is....
Numerical answer
View written solutionFree

Correct answer: 12

  1. Identify the relevant redox change

In neutral or faintly alkaline medium, permanganate is reduced as:

MnO4−+2H2O+3e−→MnO2+4OH−\mathrm{MnO_4^- + 2H_2O + 3e^- \rightarrow MnO_2 + 4OH^-}MnO4−​+2H2​O+3e−→MnO2​+4OH−

So, 1 mole of MnO4−\mathrm{MnO_4^-}MnO4−​ accepts 3 moles of electrons.

Hence, 8 moles of permanganate accept:

8×3=24 moles of electrons8 \times 3 = 24 \text{ moles of electrons}8×3=24 moles of electrons
  1. Oxidation of thiosulphate in neutral/alkaline medium

Thiosulphate ion S2O32−\mathrm{S_2O_3^{2-}}S2​O32−​ is oxidised quantitatively to tetrathionate:

2 S2O32−→S4O62−+2e−2\,\mathrm{S_2O_3^{2-}} \rightarrow \mathrm{S_4O_6^{2-}} + 2e^-2S2​O32−​→S4​O62−​+2e−

This shows that:

  • 2 moles of thiosulphate produce 1 mole of S4O62−\mathrm{S_4O_6^{2-}}S4​O62−​
  • and release 2 moles of electrons.

So, 1 mole of S4O62−\mathrm{S_4O_6^{2-}}S4​O62−​ corresponds to 2 electrons released.


  1. Match electrons exchanged

Total electrons accepted by permanganate =24=24=24.

Therefore, electrons released by thiosulphate oxidation must also be 24.

Since formation of 1 mole of tetrathionate gives 2 electrons,

X=242=12X = \frac{24}{2} = 12X=224​=12

Thus, the sulphur-containing product formed is 12 moles of S4O62−\mathrm{S_4O_6^{2-}}S4​O62−​.


  1. Final answer
12\boxed{12}12​
  1. Comparison with stored correct answer

Stored correct answer = 666

My derived answer = 121212

These do not match. The likely reason is that the stored answer may have used an incorrect oxidation product or electron count. In neutral/faintly alkaline medium, thiosulphate is oxidised to tetrathionate, and using the standard half-reactions gives X=12X=12X=12.

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