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Correct answer: 12
- Identify the relevant redox change
In neutral or faintly alkaline medium, permanganate is reduced as:
So, 1 mole of accepts 3 moles of electrons.
Hence, 8 moles of permanganate accept:
- Oxidation of thiosulphate in neutral/alkaline medium
Thiosulphate ion is oxidised quantitatively to tetrathionate:
This shows that:
- 2 moles of thiosulphate produce 1 mole of
- and release 2 moles of electrons.
So, 1 mole of corresponds to 2 electrons released.
- Match electrons exchanged
Total electrons accepted by permanganate .
Therefore, electrons released by thiosulphate oxidation must also be 24.
Since formation of 1 mole of tetrathionate gives 2 electrons,
Thus, the sulphur-containing product formed is 12 moles of .
- Final answer
- Comparison with stored correct answer
Stored correct answer =
My derived answer =
These do not match. The likely reason is that the stored answer may have used an incorrect oxidation product or electron count. In neutral/faintly alkaline medium, thiosulphate is oxidised to tetrathionate, and using the standard half-reactions gives .
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