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Redox Reactions question

2021 · Shift 2 · Q19
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Redox Reactions question

2021 · Shift 2 · Q19

JEE AdvancedChemistryRedox ReactionsNumerical+4 / −1
Ozonolysis of ClO2ClO_2ClO2​ produces an oxide of chlorine. The average oxidation state of chlorine in this oxide is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 6

Step-by-step Solution:

  1. Identify the Reactants and Reaction: The problem describes the ozonolysis of chlorine dioxide (ClO2ClO_2ClO2​). This means ClO2ClO_2ClO2​ is reacting with ozone (O3O_3O3​). Both are strong oxidizing agents, but ozone is generally stronger and will oxidize the chlorine in ClO2ClO_2ClO2​.

  2. Determine the Oxidation State of Chlorine in the Reactant: In chlorine dioxide (ClO2ClO_2ClO2​), let the oxidation state of chlorine be xxx. The oxidation state of oxygen is typically -2. x+2(−2)=0x + 2(-2) = 0x+2(−2)=0 x−4=0x - 4 = 0x−4=0 x=+4x = +4x=+4 So, the initial oxidation state of chlorine is +4.

  3. Write the Chemical Reaction: Ozone (O3O_3O3​) will oxidize ClO2ClO_2ClO2​ to a higher oxidation state oxide of chlorine. The balanced chemical reaction for the ozonolysis of ClO2ClO_2ClO2​ is: 2ClO2+2O3→Cl2O6+2O22ClO_2 + 2O_3 \rightarrow Cl_2O_6 + 2O_22ClO2​+2O3​→Cl2​O6​+2O2​ This reaction produces dichlorine hexoxide (Cl2O6Cl_2O_6Cl2​O6​) and oxygen gas.

  4. Identify the Product Oxide: The oxide of chlorine formed is dichlorine hexoxide, with the chemical formula Cl2O6Cl_2O_6Cl2​O6​.

  5. Calculate the Average Oxidation State of Chlorine in the Product: To find the average oxidation state of chlorine in Cl2O6Cl_2O_6Cl2​O6​, we again use the rule that the sum of oxidation states in a neutral compound is zero. Let the average oxidation state of chlorine be yyy. The oxidation state of oxygen is -2. The equation for the sum of oxidation states in Cl2O6Cl_2O_6Cl2​O6​ is: 2(y)+6(−2)=02(y) + 6(-2) = 02(y)+6(−2)=0 2y−12=02y - 12 = 02y−12=0 2y=122y = 122y=12 y=+6y = +6y=+6

    Alternatively, Cl2O6Cl_2O_6Cl2​O6​ exists in an ionic form as chloryl perchlorate, [ClO2]+[ClO4]−[ClO_2]^+[ClO_4]^-[ClO2​]+[ClO4​]−.

    • In the cation [ClO2]+[ClO_2]^+[ClO2​]+, the oxidation state of Cl is +5 (since x+2(−2)=+1⇒x=+5x + 2(-2) = +1 \Rightarrow x = +5x+2(−2)=+1⇒x=+5).
    • In the anion [ClO4]−[ClO_4]^-[ClO4​]−, the oxidation state of Cl is +7 (since x+4(−2)=−1⇒x=+7x + 4(-2) = -1 \Rightarrow x = +7x+4(−2)=−1⇒x=+7). The average oxidation state is the average of these two values: Average Oxidation State=(+5)+(+7)2=122=+6\text{Average Oxidation State} = \frac{(+5) + (+7)}{2} = \frac{12}{2} = +6Average Oxidation State=2(+5)+(+7)​=212​=+6
  6. Final Answer: The average oxidation state of chlorine in the resulting oxide (Cl2O6Cl_2O_6Cl2​O6​) is 6.

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