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Correct answer: 6
Step-by-step Solution:
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Identify the Reactants and Reaction: The problem describes the ozonolysis of chlorine dioxide (). This means is reacting with ozone (). Both are strong oxidizing agents, but ozone is generally stronger and will oxidize the chlorine in .
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Determine the Oxidation State of Chlorine in the Reactant: In chlorine dioxide (), let the oxidation state of chlorine be . The oxidation state of oxygen is typically -2. So, the initial oxidation state of chlorine is +4.
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Write the Chemical Reaction: Ozone () will oxidize to a higher oxidation state oxide of chlorine. The balanced chemical reaction for the ozonolysis of is: This reaction produces dichlorine hexoxide () and oxygen gas.
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Identify the Product Oxide: The oxide of chlorine formed is dichlorine hexoxide, with the chemical formula .
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Calculate the Average Oxidation State of Chlorine in the Product: To find the average oxidation state of chlorine in , we again use the rule that the sum of oxidation states in a neutral compound is zero. Let the average oxidation state of chlorine be . The oxidation state of oxygen is -2. The equation for the sum of oxidation states in is:
Alternatively, exists in an ionic form as chloryl perchlorate, .
- In the cation , the oxidation state of Cl is +5 (since ).
- In the anion , the oxidation state of Cl is +7 (since ). The average oxidation state is the average of these two values:
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Final Answer: The average oxidation state of chlorine in the resulting oxide () is 6.
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