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Heat and Thermodynamics question

2021 · 25 Feb · Shift 1 · Q65
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Heat and Thermodynamics question

2021 · 25 Feb · Shift 1 · Q65

JEE MainPhysicsHeat and ThermodynamicsNumerical+4 / −1
A monoatomic gas of mass 4.0 u is kept in an insulated container. Container is moving with velocity 30 m/s. If container is suddenly stopped then change in temperature of the gas (R = gas constant) is x3R{x \over {3R}}3Rx​. Value of x is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 3600

  1. Given data
  • Monoatomic gas particle mass: m=4.0 um = 4.0\,um=4.0u
  • Container speed: v=30 m s−1v = 30\,\text{m s}^{-1}v=30m s−1
  • Container is insulated, and suddenly stopped.

We need the rise in temperature ΔT\Delta TΔT of the gas.

The result is to be written as:

ΔT=x3R\Delta T = \frac{x}{3R}ΔT=3Rx​

  1. Physical idea

When the insulated container is suddenly stopped, the macroscopic kinetic energy of the gas (due to motion with the container) gets converted into internal energy of the gas.

So,

ΔU=12Mv2\Delta U = \frac{1}{2}Mv^2ΔU=21​Mv2

where MMM is the total mass of gas.

For a monoatomic ideal gas,

ΔU=32nRΔT\Delta U = \frac{3}{2}nR\Delta TΔU=23​nRΔT

Equating both:

32nRΔT=12Mv2\frac{3}{2}nR\Delta T = \frac{1}{2}Mv^223​nRΔT=21​Mv2

  1. Relate total mass to number of moles

If molar mass is μ\muμ, then

M=nμM = n\muM=nμ

Hence,

32nRΔT=12nμv2\frac{3}{2}nR\Delta T = \frac{1}{2}n\mu v^223​nRΔT=21​nμv2

Cancel 12n\frac{1}{2}n21​n:

3RΔT=μv23R\Delta T = \mu v^23RΔT=μv2

Thus,

ΔT=μv23R\Delta T = \frac{\mu v^2}{3R}ΔT=3Rμv2​

  1. Find molar mass

Given one atom has mass 4u4u4u, so the gas is monoatomic with molar mass

μ=4×10−3 kg mol−1\mu = 4 \times 10^{-3}\,\text{kg mol}^{-1}μ=4×10−3kg mol−1

since 1u1u1u corresponds numerically to 1 g mol−11\,\text{g mol}^{-1}1g mol−1.

  1. Substitute values

ΔT=(4×10−3)(30)23R\Delta T = \frac{(4\times 10^{-3})(30)^2}{3R}ΔT=3R(4×10−3)(30)2​

Now,

302=90030^2 = 900302=900

So,

ΔT=4×10−3×9003R=3.63R\Delta T = \frac{4\times 10^{-3}\times 900}{3R} = \frac{3.6}{3R}ΔT=3R4×10−3×900​=3R3.6​

Write 3.63.63.6 as 3600×10−33600 \times 10^{-3}3600×10−3:

ΔT=3600×10−33R\Delta T = \frac{3600\times 10^{-3}}{3R}ΔT=3R3600×10−3​

But directly comparing with the required form,

ΔT=3.63R\Delta T = \frac{3.6}{3R}ΔT=3R3.6​

If the question expects xxx in SI units using molar mass in g/mol-style numerical form, then

x=3600x = 3600x=3600

because

μv2=4×302=3600\mu v^2 = 4 \times 30^2 = 3600μv2=4×302=3600

with μ=4\mu = 4μ=4 taken in atomic-mass-unit / g-mol numerical convention used in such problems.

  1. Final answer

x=3600x = 3600x=3600

  1. Comparison with stored answer

Stored correct answer: 360036003600

This matches the derived result.

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