JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
For a gas CP CV = R in a state P and CP CV = 1.10 R in a state Q, TP and TQ are the temperatures in two different states P and Q respectively. Then
- ATP = TQ
- BTP < TQ
- CTP = 0.9 TQ
- DTP > TQ
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Correct answer: D
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For a perfect (ideal) gas, the Mayer relation is and it is independent of temperature.
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But here the question states:
- At state :
- At state :
Since the difference is not constant, this indicates the gas is not ideal.
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For a real gas, we use the general thermodynamic relation:
This can also be written as where is the coefficient of volume expansion and is the isothermal compressibility.
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From this general relation, is generally proportional to temperature (for a given substance/state dependence), so a larger value of corresponds to a larger temperature.
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Comparing the two states: hence or
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Therefore, the correct option is:
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Check the given options:
- A: ❌
- B: ✅
- C: ❌ (this exact proportionality is not justified)
- D: ❌
So the best conclusion is only
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