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Heat and Thermodynamics question

2021 · 24 Feb · Shift 2 · Q48
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Heat and Thermodynamics question

2021 · 24 Feb · Shift 2 · Q48

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
If one mole of an ideal gas at (P1, V1) is allowed to expand reversibly and isothermally (A to B) its pressure is reduced to one-half of the original pressure (see figure). This is followed by a constant volume cooling till its pressure is reduced to one-fourth of the initial value (B →\to→ C). Then it is restored to its initial state by a reversible adiabatic compression (C to A). The net workdone by the gas is equal to : JEE Main 2021 (Online) 24th February Evening Shift Physics - Heat and Thermodynamics Question 273 English
  1. A
    −RT2(γ−1)- {{RT} \over {2(\gamma - 1)}}−2(γ−1)RT​
  2. B
    RT(ln⁡2−12(γ−1))RT\left( {\ln 2 - {1 \over {2(\gamma - 1)}}} \right)RT(ln2−2(γ−1)1​)
  3. C
    RTln⁡2RT\ln 2RTln2
  4. D
    000
View written solutionFree

Correct answer: B

  1. State the three processes

For one mole of ideal gas:

  • Initial state A=(P1,V1)A=(P_1,V_1)A=(P1​,V1​)
  • A→BA \to BA→B: reversible isothermal expansion
  • B→CB \to CB→C: constant volume cooling
  • C→AC \to AC→A: reversible adiabatic compression

We need the net work done by the gas: Wnet=WAB+WBC+WCAW_{\text{net}}=W_{AB}+W_{BC}+W_{CA}Wnet​=WAB​+WBC​+WCA​


  1. Process A→BA \to BA→B: Isothermal expansion

Since the process is isothermal for one mole of ideal gas, P1V1=RTP_1V_1=RTP1​V1​=RT

Pressure is reduced to half: PB=P12P_B=\frac{P_1}{2}PB​=2P1​​

For isothermal process, PV=constantPV=\text{constant}PV=constant, so P1V1=PBVBP_1V_1=P_BV_BP1​V1​=PB​VB​ P1V1=P12VB⇒VB=2V1P_1V_1=\frac{P_1}{2}V_B \Rightarrow V_B=2V_1P1​V1​=2P1​​VB​⇒VB​=2V1​

Work done in reversible isothermal expansion: WAB=RTln⁡VBVA=RTln⁡2V1V1=RTln⁡2W_{AB}=RT\ln\frac{V_B}{V_A}=RT\ln\frac{2V_1}{V_1}=RT\ln 2WAB​=RTlnVA​VB​​=RTlnV1​2V1​​=RTln2


  1. Process B→CB \to CB→C: Constant volume cooling

At constant volume, WBC=0W_{BC}=0WBC​=0

Also, since pressure is reduced to one-fourth of initial pressure, PC=P14P_C=\frac{P_1}{4}PC​=4P1​​

And because B→CB \to CB→C is at constant volume, VC=VB=2V1V_C=V_B=2V_1VC​=VB​=2V1​

So state CCC is: C(P14,2V1)C\left(\frac{P_1}{4},2V_1\right)C(4P1​​,2V1​)


  1. Process C→AC \to AC→A: Reversible adiabatic compression

For a reversible adiabatic process, TVγ−1=constantTV^{\gamma-1}=\text{constant}TVγ−1=constant

Let temperature at AAA be TA=TT_A=TTA​=T.

At state CCC, TC=PCVCR=(P14)(2V1)RT_C=\frac{P_CV_C}{R}=\frac{\left(\frac{P_1}{4}\right)(2V_1)}{R}TC​=RPC​VC​​=R(4P1​​)(2V1​)​ Using P1V1=RTP_1V_1=RTP1​V1​=RT, TC=12⋅P1V1R=T2T_C=\frac{1}{2}\cdot \frac{P_1V_1}{R}=\frac{T}{2}TC​=21​⋅RP1​V1​​=2T​

Now compute work in adiabatic compression. For one mole, WCA=R(TC−TA)γ−1W_{CA}=\frac{R(T_C-T_A)}{\gamma-1}WCA​=γ−1R(TC​−TA​)​ This gives work done by the gas during compression, which is negative.

Substitute TC=T2T_C=\frac{T}{2}TC​=2T​ and TA=TT_A=TTA​=T: WCA=R(T2−T)γ−1W_{CA}=\frac{R\left(\frac{T}{2}-T\right)}{\gamma-1}WCA​=γ−1R(2T​−T)​ WCA=−RT2(γ−1)W_{CA}=-\frac{RT}{2(\gamma-1)}WCA​=−2(γ−1)RT​


  1. Net work done

Wnet=WAB+WBC+WCAW_{\text{net}}=W_{AB}+W_{BC}+W_{CA}Wnet​=WAB​+WBC​+WCA​ Wnet=RTln⁡2+0−RT2(γ−1)W_{\text{net}}=RT\ln 2+0-\frac{RT}{2(\gamma-1)}Wnet​=RTln2+0−2(γ−1)RT​

Therefore, Wnet=RT(ln⁡2−12(γ−1))W_{\text{net}}=RT\left(\ln 2-\frac{1}{2(\gamma-1)}\right)Wnet​=RT(ln2−2(γ−1)1​)


  1. Match with options

This matches:

Option B RT(ln⁡2−12(γ−1))RT\left(\ln 2-\frac{1}{2(\gamma-1)}\right)RT(ln2−2(γ−1)1​)


  1. Comparison with stored correct answer

Stored correct answer: B

Our derived answer: B

So, the answer agrees with the stored correct answer.

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