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Heat and Thermodynamics question

2020 · 5 Sep · Shift 1 · Q63
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Heat and Thermodynamics question

2020 · 5 Sep · Shift 1 · Q63

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Three different processes that can occur in an ideal monoatomic gas are shown in the P vs V diagram. The paths are labelled as A →\to→ B, A →\to→ C and A →\to→ D. The change in internal energies during these process are taken as EAB, EAC and EAD and the work done as WAB, WAC and WAD. The correct relation between these parameters are : JEE Main 2020 (Online) 5th September Morning Slot Physics - Heat and Thermodynamics Question 288 English
  1. A
    EAB < EAC < EAD, WAB > 0, WAC > WAD
  2. B
    EAB = EAC = EAD, WAB > 0, WAC = 0, WAD < 0
  3. C
    EAB > EAC > EAD, WAB < WAC < WAD
  4. D
    EAB = EAC < EAD, WAB > 0, WAC = 0, WAD < 0
View written solutionFree

Correct answer: B

  1. Key idea: internal energy of an ideal monoatomic gas

For an ideal gas, U=32nRTU = \frac{3}{2}nRTU=23​nRT so the change in internal energy depends only on temperature: ΔU=32nRΔT\Delta U = \frac{3}{2}nR\Delta TΔU=23​nRΔT Using the ideal gas law, PV=nRTPV = nRTPV=nRT we see that temperature depends only on the product PVPVPV.

So if the final states B,C,DB, C, DB,C,D are such that PBVB=PCVC=PDVD,P_BV_B = P_CV_C = P_DV_D,PB​VB​=PC​VC​=PD​VD​, then TB=TC=TDT_B = T_C = T_DTB​=TC​=TD​ and hence EAB=EAC=EAD.E_{AB} = E_{AC} = E_{AD}.EAB​=EAC​=EAD​.

This is the standard interpretation of such a diagram: the three processes start from the same initial point AAA and end at different points lying on the same isotherm.


  1. Work done in each process

Work done by the gas is W=∫P dVW = \int P\,dVW=∫PdV So the sign of work depends on whether volume increases, stays constant, or decreases.

  • Process A→BA \to BA→B: volume increases, so WAB>0W_{AB} > 0WAB​>0

  • Process A→CA \to CA→C: this is vertical in the PPP-VVV diagram (isochoric), so dV=0  ⟹  WAC=0dV=0 \implies W_{AC}=0dV=0⟹WAC​=0

  • Process A→DA \to DA→D: volume decreases, so WAD<0W_{AD} < 0WAD​<0


  1. Compare with options

We obtained: EAB=EAC=EAD,WAB>0,WAC=0,WAD<0E_{AB}=E_{AC}=E_{AD}, \qquad W_{AB}>0, \qquad W_{AC}=0, \qquad W_{AD}<0EAB​=EAC​=EAD​,WAB​>0,WAC​=0,WAD​<0

This matches Option B exactly.


  1. Final answer

The correct relation is: EAB=EAC=EAD,WAB>0,WAC=0,WAD<0E_{AB}=E_{AC}=E_{AD}, \quad W_{AB}>0, \quad W_{AC}=0, \quad W_{AD}<0EAB​=EAC​=EAD​,WAB​>0,WAC​=0,WAD​<0 So the correct option is B.

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