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Heat and Thermodynamics question

2020 · 5 Sep · Shift 2 · Q36
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  5. /2020 · 5 Sep · Shift 2 · Q36

Heat and Thermodynamics question

2020 · 5 Sep · Shift 2 · Q36

JEE MainPhysicsHeat and ThermodynamicsNumerical+4 / −1
Nitrogen gas is at 300oC temperature. The temperature (in K) at which the rms speed of a H2 molecule would be equal to the rms speed of a nitrogen molecule, is ‾\underline{\hspace{2cm}}​. (Molar mass of N2 gas 28 g).
Numerical answer
View written solutionFree

Correct answer: 40TO41

  1. The rms speed of a gas molecule is

vrms=3RTMv_{\text{rms}}=\sqrt{\frac{3RT}{M}}vrms​=M3RT​​

where:

  • TTT = absolute temperature,
  • MMM = molar mass.
  1. We are given that nitrogen gas (N2\mathrm{N_2}N2​) is at 300∘C300^\circ \mathrm{C}300∘C. Convert to Kelvin:

TN2=300+273=573 KT_{N_2}=300+273=573\,\text{K}TN2​​=300+273=573K

  1. Let the required temperature of hydrogen gas (H2\mathrm{H_2}H2​) be THT_HTH​. For equal rms speeds:

3RTHMH2=3RTN2MN2\sqrt{\frac{3RT_H}{M_{H_2}}}=\sqrt{\frac{3RT_{N_2}}{M_{N_2}}}MH2​​3RTH​​​=MN2​​3RTN2​​​​

Squaring both sides:

THMH2=TN2MN2\frac{T_H}{M_{H_2}}=\frac{T_{N_2}}{M_{N_2}}MH2​​TH​​=MN2​​TN2​​​

So,

TH=TN2⋅MH2MN2T_H=T_{N_2}\cdot \frac{M_{H_2}}{M_{N_2}}TH​=TN2​​⋅MN2​​MH2​​​

  1. Substitute values:
  • MH2=2 g mol−1M_{H_2}=2\,\text{g mol}^{-1}MH2​​=2g mol−1
  • MN2=28 g mol−1M_{N_2}=28\,\text{g mol}^{-1}MN2​​=28g mol−1
  • TN2=573 KT_{N_2}=573\,\text{K}TN2​​=573K

TH=573×228=573×114T_H=573\times \frac{2}{28}=573\times \frac{1}{14}TH​=573×282​=573×141​

TH=40.93 KT_H=40.93\,\text{K}TH​=40.93K

  1. Therefore, the required temperature is approximately

41 K\boxed{41\,\text{K}}41K​

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