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Heat and Thermodynamics question

2020 · 7 Jan · Shift 1 · Q45
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Heat and Thermodynamics question

2020 · 7 Jan · Shift 1 · Q45

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
A litre of dry air at STP expands adiabatically to a volume of 3 litres. If γ\gammaγ = 1.40, the work done by air is : (31.4 = 4.6555) [Take air to be an ideal gas]
  1. A
    60.7 J
  2. B
    100.8 J
  3. C
    90.5 J
  4. D
    48 J
View written solutionFree

Correct answer: C

  1. Given data
  • Initial volume: V1=1 litre=10−3 m3V_1 = 1\text{ litre} = 10^{-3}\,\text{m}^3V1​=1 litre=10−3m3
  • Final volume: V2=3 litreV_2 = 3\text{ litre}V2​=3 litre
  • Initial state is STP, so: P1=1.013×105 Pa,T1=273 KP_1 = 1.013\times 10^5\,\text{Pa}, \qquad T_1 = 273\,\text{K}P1​=1.013×105Pa,T1​=273K
  • Adiabatic index: γ=1.40\gamma = 1.40γ=1.40

We need the work done by the gas during adiabatic expansion.


  1. Use adiabatic relation

For an adiabatic process of an ideal gas: P1V1γ=P2V2γP_1 V_1^{\gamma} = P_2 V_2^{\gamma}P1​V1γ​=P2​V2γ​ So, P2=P1(V1V2)γP_2 = P_1\left(\frac{V_1}{V_2}\right)^{\gamma}P2​=P1​(V2​V1​​)γ

Here, V1V2=13\frac{V_1}{V_2} = \frac{1}{3}V2​V1​​=31​ Hence, P2=P1(13)1.4P_2 = P_1\left(\frac{1}{3}\right)^{1.4}P2​=P1​(31​)1.4

Now, 31.4=3⋅30.43^{1.4} = 3\cdot 3^{0.4}31.4=3⋅30.4 Given: 30.4=1.55183^{0.4} = 1.551830.4=1.5518 Therefore, 31.4=3×1.5518=4.6554≈4.65553^{1.4} = 3\times 1.5518 = 4.6554 \approx 4.655531.4=3×1.5518=4.6554≈4.6555 So, (13)1.4=14.6555\left(\frac{1}{3}\right)^{1.4} = \frac{1}{4.6555}(31​)1.4=4.65551​ Thus, P2=P14.6555P_2 = \frac{P_1}{4.6555}P2​=4.6555P1​​


  1. Formula for work done in adiabatic process

Work done by gas: W=P1V1−P2V2γ−1W = \frac{P_1V_1 - P_2V_2}{\gamma - 1}W=γ−1P1​V1​−P2​V2​​

Now compute each term.

First, P1V1=1.013×105×10−3=101.3 JP_1V_1 = 1.013\times 10^5 \times 10^{-3} = 101.3\,\text{J}P1​V1​=1.013×105×10−3=101.3J

Next,

= P_1V_1\cdot \frac{3}{4.6555}$$ So, $$P_2V_2 = 101.3\times \frac{3}{4.6555}$$ Now, $$\frac{3}{4.6555} \approx 0.6444$$ Thus, $$P_2V_2 \approx 101.3\times 0.6444 \approx 65.28\,\text{J}$$ --- 4. **Calculate work** Since $$\gamma - 1 = 1.4 - 1 = 0.4$$ Therefore, $$W = \frac{101.3 - 65.28}{0.4}$$ $$W = \frac{36.02}{0.4}$$ $$W \approx 90.05\,\text{J}$$ With rounding, this matches: $$W \approx 90.5\,\text{J}$$ --- 5. **Check options** - A: $60.7\,\text{J}$ ❌ - B: $100.8\,\text{J}$ ❌ - C: $90.5\,\text{J}$ ✅ - D: $48\,\text{J}$ ❌ --- 6. **Final answer** The work done by the air is: $$\boxed{90.5\,\text{J}}$$ So, the correct option is **C**.
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