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Heat and Thermodynamics question

2020 · 6 Sep · Shift 2 · Q41
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Heat and Thermodynamics question

2020 · 6 Sep · Shift 2 · Q41

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
In a dilute gas at pressure P and temperature T, the mean time between successive collisions of a molecule varies with T as :
  1. A
    T\sqrt TT​
  2. B
    T
  3. C
    1T{1 \over T}T1​
  4. D
    1T{1 \over {\sqrt T }}T​1​
View written solutionFree

Correct answer: A

  1. Use the relation for mean free time

The mean time between successive collisions is

au=λvˉ au = \frac{\lambda}{\bar v}au=vˉλ​

where:

  • λ\lambdaλ = mean free path
  • vˉ\bar vvˉ = average molecular speed

  1. Find how mean free path depends on TTT at constant pressure

For a dilute gas,

λ=12 nσ\lambda = \frac{1}{\sqrt{2}\,n\sigma}λ=2​nσ1​

where nnn is number density and σ\sigmaσ is collision cross-section.

Using the ideal gas law,

P=nkT  ⟹  n=PkTP = nkT \implies n = \frac{P}{kT}P=nkT⟹n=kTP​

Since PPP is constant,

n∝1Tn \propto \frac{1}{T}n∝T1​

Hence,

λ∝1n∝T\lambda \propto \frac{1}{n} \propto Tλ∝n1​∝T


  1. Find how average speed depends on TTT

For gas molecules,

vˉ∝T\bar v \propto \sqrt{T}vˉ∝T​


  1. Now find the dependence of τ\tauτ on TTT

τ=λvˉ∝TT=T\tau = \frac{\lambda}{\bar v} \propto \frac{T}{\sqrt{T}} = \sqrt{T}τ=vˉλ​∝T​T​=T​

So the mean time between collisions varies as

T\boxed{\sqrt{T}}T​​


  1. Check options
  • A: T\sqrt{T}T​ ✅
  • B: TTT ❌
  • C: 1T\dfrac{1}{T}T1​ ❌
  • D: 1T\dfrac{1}{\sqrt{T}}T​1​ ❌

Therefore, the correct option is

A\boxed{A}A​


  1. Comparison with stored answer

Stored correct answer: DDD

My derived answer is AAA. The stored answer appears incorrect because at constant pressure, number density decreases as 1/T1/T1/T, making mean free path increase as TTT, while molecular speed increases only as T\sqrt{T}T​. Therefore the collision time increases as T\sqrt{T}T​, not decreases as 1/T1/\sqrt{T}1/T​.

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