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Heat and Thermodynamics question

2020 · 2 Sep · Shift 1 · Q60
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Heat and Thermodynamics question

2020 · 2 Sep · Shift 1 · Q60

JEE MainPhysicsHeat and ThermodynamicsNumerical+4 / −1
An engine takes in 5 moles of air at 20oC and 1 atm, and compresses it adiabatically to 1/10th of the original volume. Assuming air to be a diatomic ideal gas made up of rigid molecules, the change in its internal energy during this process comes out to be X kJ. The value of X to the nearest integer is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 46

  1. Given data
  • Number of moles: n=5n = 5n=5
  • Initial temperature: T1=20∘C=293 KT_1 = 20^\circ C = 293\,KT1​=20∘C=293K
  • Adiabatic compression to V2=V110V_2 = \frac{V_1}{10}V2​=10V1​​
  • Air is a diatomic ideal gas with rigid molecules

For a diatomic rigid gas, CV=52R,γ=CPCV=75C_V = \frac{5}{2}R, \qquad \gamma = \frac{C_P}{C_V} = \frac{7}{5}CV​=25​R,γ=CV​CP​​=57​

We need the change in internal energy: ΔU=nCV(T2−T1)\Delta U = n C_V (T_2 - T_1)ΔU=nCV​(T2​−T1​)

  1. Use adiabatic relation to find T2T_2T2​

For an adiabatic process of an ideal gas, TVγ−1=constantT V^{\gamma-1} = \text{constant}TVγ−1=constant

So, T1V1γ−1=T2V2γ−1T_1 V_1^{\gamma-1} = T_2 V_2^{\gamma-1}T1​V1γ−1​=T2​V2γ−1​

Hence, T2T1=(V1V2)γ−1\frac{T_2}{T_1} = \left(\frac{V_1}{V_2}\right)^{\gamma-1}T1​T2​​=(V2​V1​​)γ−1

Since V1V2=10,γ−1=75−1=25\frac{V_1}{V_2} = 10, \qquad \gamma - 1 = \frac{7}{5} - 1 = \frac{2}{5}V2​V1​​=10,γ−1=57​−1=52​

Therefore, T2T1=102/5\frac{T_2}{T_1} = 10^{2/5}T1​T2​​=102/5

Now, 102/5≈2.51210^{2/5} \approx 2.512102/5≈2.512

Thus, T2=293×2.512≈736 KT_2 = 293 \times 2.512 \approx 736\,KT2​=293×2.512≈736K

So, ΔT=T2−T1=736−293=443 K\Delta T = T_2 - T_1 = 736 - 293 = 443\,KΔT=T2​−T1​=736−293=443K

  1. Calculate change in internal energy

ΔU=nCVΔT\Delta U = n C_V \Delta TΔU=nCV​ΔT

With CV=52RC_V = \frac{5}{2}RCV​=25​R

So, ΔU=5×52R×443\Delta U = 5 \times \frac{5}{2}R \times 443ΔU=5×25​R×443

Using R=8.314 J mol−1K−1R = 8.314\,\text{J mol}^{-1}\text{K}^{-1}R=8.314J mol−1K−1,

ΔU=12.5×8.314×443\Delta U = 12.5 \times 8.314 \times 443ΔU=12.5×8.314×443

ΔU≈46031 J\Delta U \approx 46031\,\text{J}ΔU≈46031J

ΔU≈46.0 kJ\Delta U \approx 46.0\,\text{kJ}ΔU≈46.0kJ

  1. Nearest integer

X=46X = 46X=46

  1. Comparison with stored answer

Stored correct answer = 464646

This matches our derived value.

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