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Heat and Thermodynamics question

2020 · 3 Sep · Shift 1 · Q47
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Heat and Thermodynamics question

2020 · 3 Sep · Shift 1 · Q47

JEE MainPhysicsHeat and ThermodynamicsNumerical+4 / −1
A bakelite beaker has volume capacity of 500 cc at 30oC. When it is partially filled with Vm volume (at 30oC) of mercury, it is found that the unfilled volume of the beaker remains constant as temperature is varied. If γ\gammaγ(beaker) = 6 × 10–6 oC–1 and γ\gammaγ(mercury) = 1.5 × 10–4 oC–1, where γ\gammaγ is the coefficient of volume expansion, then Vm (in cc) is close to ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 20

  1. Given data
  • Capacity of beaker at 30∘C30^\circ\text{C}30∘C: Vb=500 ccV_b = 500\ \text{cc}Vb​=500 cc
  • Volume of mercury filled at 30∘C30^\circ\text{C}30∘C: Vm=?V_m = ?Vm​=?
  • Coefficient of volume expansion of beaker: γb=6×10−6 ∘C−1\gamma_b = 6\times 10^{-6}\ ^\circ\text{C}^{-1}γb​=6×10−6 ∘C−1
  • Coefficient of volume expansion of mercury: γm=1.5×10−4 ∘C−1\gamma_m = 1.5\times 10^{-4}\ ^\circ\text{C}^{-1}γm​=1.5×10−4 ∘C−1

The unfilled volume remains constant when temperature changes.


  1. Expression for unfilled volume

At temperature change ΔT\Delta TΔT, the beaker capacity becomes Vb′=500(1+γbΔT)V_b' = 500(1+\gamma_b \Delta T)Vb′​=500(1+γb​ΔT)

The mercury volume becomes Vm′=Vm(1+γmΔT)V_m' = V_m(1+\gamma_m \Delta T)Vm′​=Vm​(1+γm​ΔT)

So the unfilled volume is Vempty=Vb′−Vm′V_{\text{empty}} = V_b' - V_m'Vempty​=Vb′​−Vm′​ Vempty=500(1+γbΔT)−Vm(1+γmΔT)V_{\text{empty}} = 500(1+\gamma_b\Delta T) - V_m(1+\gamma_m\Delta T)Vempty​=500(1+γb​ΔT)−Vm​(1+γm​ΔT)

We are told this remains constant as temperature varies. Therefore, the coefficient of ΔT\Delta TΔT must be zero.


  1. Set temperature-dependent part to zero

From Vempty=(500−Vm)+(500γb−Vmγm)ΔTV_{\text{empty}} = (500 - V_m) + (500\gamma_b - V_m\gamma_m)\Delta TVempty​=(500−Vm​)+(500γb​−Vm​γm​)ΔT

For this to be independent of temperature, 500γb−Vmγm=0500\gamma_b - V_m\gamma_m = 0500γb​−Vm​γm​=0

So, Vm=500γbγmV_m = \frac{500\gamma_b}{\gamma_m}Vm​=γm​500γb​​

Substitute values: Vm=500×6×10−61.5×10−4V_m = \frac{500\times 6\times 10^{-6}}{1.5\times 10^{-4}}Vm​=1.5×10−4500×6×10−6​


  1. Calculate

6×10−61.5×10−4=61.5×10−2=4×10−2=0.04\frac{6\times 10^{-6}}{1.5\times 10^{-4}} = \frac{6}{1.5}\times 10^{-2} = 4\times 10^{-2} = 0.041.5×10−46×10−6​=1.56​×10−2=4×10−2=0.04

Thus, Vm=500×0.04=20 ccV_m = 500\times 0.04 = 20\ \text{cc}Vm​=500×0.04=20 cc


  1. Final answer

20\boxed{20}20​

The required volume of mercury is 20 cc.

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