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Heat and Thermodynamics question

2020 · 3 Sep · Shift 2 · Q51
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Heat and Thermodynamics question

2020 · 3 Sep · Shift 2 · Q51

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
To raise the temperature of a certain mass of gas by 50oC at a constant pressure, 160 calories of heat is required. When the same mass of gas is cooled by 100oC at constant volume, 240 calories of heat is released. How many degrees of freedom does each molecule of this gas have (assume gas to be ideal)?
  1. A
    6
  2. B
    7
  3. C
    5
  4. D
    3
View written solutionFree

Correct answer: A

  1. Use heat capacities from the given processes

For a fixed mass of an ideal gas:

  • At constant pressure: Q=nCpΔTQ = n C_p \Delta TQ=nCp​ΔT
  • At constant volume: Q=nCvΔTQ = n C_v \Delta TQ=nCv​ΔT

We are given:

  • Heating by 50∘C50^\circ C50∘C at constant pressure requires 160160160 cal: nCp⋅50=160nC_p \cdot 50 = 160nCp​⋅50=160 nCp=16050=3.2 cal/∘CnC_p = \frac{160}{50} = 3.2\ \text{cal/}^\circ CnCp​=50160​=3.2 cal/∘C

  • Cooling by 100∘C100^\circ C100∘C at constant volume releases 240240240 cal:

Magnitude-wise, nCv⋅100=240nC_v \cdot 100 = 240nCv​⋅100=240 nCv=240100=2.4 cal/∘CnC_v = \frac{240}{100} = 2.4\ \text{cal/}^\circ CnCv​=100240​=2.4 cal/∘C

  1. Find the ratio γ=CpCv\gamma = \dfrac{C_p}{C_v}γ=Cv​Cp​​

Since the same mass of gas is used, the factor nnn cancels: γ=CpCv=nCpnCv=3.22.4=43\gamma = \frac{C_p}{C_v} = \frac{nC_p}{nC_v} = \frac{3.2}{2.4} = \frac{4}{3}γ=Cv​Cp​​=nCv​nCp​​=2.43.2​=34​

  1. Relate γ\gammaγ to degrees of freedom

For an ideal gas with fff degrees of freedom: Cv=f2R,Cp=Cv+R=f+22RC_v = \frac{f}{2}R, \qquad C_p = C_v + R = \frac{f+2}{2}RCv​=2f​R,Cp​=Cv​+R=2f+2​R

So, γ=CpCv=f+2f\gamma = \frac{C_p}{C_v} = \frac{f+2}{f}γ=Cv​Cp​​=ff+2​

Given γ=43\gamma = \frac{4}{3}γ=34​, f+2f=43\frac{f+2}{f} = \frac{4}{3}ff+2​=34​

Cross-multiplying: 3(f+2)=4f3(f+2) = 4f3(f+2)=4f 3f+6=4f3f + 6 = 4f3f+6=4f f=6f = 6f=6

  1. Check options
  • A: 666 ✅
  • B: 777 ❌
  • C: 555 ❌
  • D: 333 ❌

Therefore, the gas molecules have 6 degrees of freedom.

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