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Thermodynamics question

2024 · 29 Jan · Shift 1 · Q14
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Thermodynamics question

2024 · 29 Jan · Shift 1 · Q14

JEE MainChemistryThermodynamicsMCQ+4 / −1
Which of the following is not correct?
  1. A
    ΔG\Delta \mathrm{G}ΔG is positive for a spontaneous reaction
  2. B
    ΔG\Delta \mathrm{G}ΔG is positive for a non-spontaneous reaction
  3. C
    ΔG\Delta \mathrm{G}ΔG is zero for a reversible reaction
  4. D
    ΔG\Delta \mathrm{G}ΔG is negative for a spontaneous reaction
View written solutionFree

Correct answer: A

  1. Recall the criterion for spontaneity using Gibbs free energy

    At constant temperature and pressure:

    • If ΔG<0\Delta G < 0ΔG<0, the process is spontaneous.
    • If ΔG>0\Delta G > 0ΔG>0, the process is non-spontaneous.
    • If ΔG=0\Delta G = 0ΔG=0, the system is at equilibrium (reversible condition).
  2. Check each option

    Option A: ΔG\Delta GΔG is positive for a spontaneous reaction

    • This is incorrect because spontaneous reactions have: ΔG<0\Delta G < 0ΔG<0

    Option B: ΔG\Delta GΔG is positive for a non-spontaneous reaction

    • This is correct because non-spontaneous reactions have: ΔG>0\Delta G > 0ΔG>0

    Option C: ΔG\Delta GΔG is zero for a reversible reaction

    • This is correct in the sense that for a reversible process at equilibrium: ΔG=0\Delta G = 0ΔG=0

    Option D: ΔG\Delta GΔG is negative for a spontaneous reaction

    • This is correct because: ΔG<0\Delta G < 0ΔG<0
  3. Identify the statement which is not correct

    The only incorrect statement is: A\boxed{\text{A}}A​

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