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Thermodynamics question

2024 · 29 Jan · Shift 2 · Q22
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Thermodynamics question

2024 · 29 Jan · Shift 2 · Q22

JEE MainChemistryThermodynamicsNumerical+4 / −1
Standard enthalpy of vapourisation for CCl4\mathrm{CCl}_4CCl4​ is 30.5 kJ mol−130.5 \mathrm{~kJ} \mathrm{~mol}^{-1}30.5 kJ mol−1. Heat required for vapourisation of 284 g284 \mathrm{~g}284 g of CCl4\mathrm{CCl}_4CCl4​ at constant temperature is ‾\underline{\hspace{2cm}}​kJ\mathrm{kJ}kJ. (Given molar mass in gmol−1;C=12,Cl=35.5\mathrm{g} \mathrm{mol}^{-1} ; \mathrm{C}=12, \mathrm{Cl}=35.5gmol−1;C=12,Cl=35.5)
Numerical answer
View written solutionFree

Correct answer: 56

  1. Find the molar mass of CCl4\mathrm{CCl_4}CCl4​

M(CCl4)=12+4(35.5)=12+142=154 g mol−1M(\mathrm{CCl_4}) = 12 + 4(35.5) = 12 + 142 = 154\ \mathrm{g\,mol^{-1}}M(CCl4​)=12+4(35.5)=12+142=154 gmol−1

  1. Calculate number of moles in 284 g284\ \mathrm{g}284 g

n=284154=14277≈1.844 moln = \frac{284}{154} = \frac{142}{77} \approx 1.844\ \mathrm{mol}n=154284​=77142​≈1.844 mol

  1. Use enthalpy of vapourisation

Given:

ΔHvap=30.5 kJ mol−1\Delta H_{vap} = 30.5\ \mathrm{kJ\,mol^{-1}}ΔHvap​=30.5 kJmol−1

Heat required:

q=n ΔHvapq = n\,\Delta H_{vap}q=nΔHvap​

q=284154×30.5q = \frac{284}{154}\times 30.5q=154284​×30.5

Since

30.5=612,284154=1427730.5 = \frac{61}{2}, \qquad \frac{284}{154}=\frac{142}{77}30.5=261​,154284​=77142​

So,

q=14277×612=71×6177q = \frac{142}{77}\times \frac{61}{2} = \frac{71\times 61}{77}q=77142​×261​=7771×61​

q=433177≈56.25 kJq = \frac{4331}{77} \approx 56.25\ \mathrm{kJ}q=774331​≈56.25 kJ

  1. Final integer answer

56\boxed{56}56​

Thus, the heat required for vapourisation of 284 g284\ \mathrm{g}284 g of CCl4\mathrm{CCl_4}CCl4​ is 56 kJ56\ \mathrm{kJ}56 kJ (approximately).

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