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Structure of Atom question

2025 · 2 Apr · Shift 2 · Q8
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Structure of Atom question

2025 · 2 Apr · Shift 2 · Q8

JEE MainChemistryStructure of AtomMCQ+4 / −1
Which of the following statements are true? (A) The subsidiary quantum number lll describes the shape of the orbital occupied by the electron. (B) JEE Main 2025 (Online) 2nd April Evening Shift Chemistry - Structure of Atom Question 7 English is the boundary surface diagram of the 2px2 \mathrm{p}_x2px​ orbital. (C) The + and - signs in the wave function of the 2px2 p_x2px​ orbital refer to charge. (D) The wave function of 2px2 \mathrm{p}_x2px​ orbital is zero everywhere in the xyx yxy plane. Choose the correct answer from the options given below :
  1. A
    (A) and (B) only
  2. B
    (B) and (D) only
  3. C
    (C) and (D) only
  4. D
    (A), (B) and (C) only
View written solutionFree

Correct answer: A

  1. Statement (A):

The subsidiary quantum number lll is also called the azimuthal quantum number. It determines the shape of the orbital.

  • l=0⇒sl=0 \Rightarrow sl=0⇒s orbital
  • l=1⇒pl=1 \Rightarrow pl=1⇒p orbital
  • l=2⇒dl=2 \Rightarrow dl=2⇒d orbital

So, (A) is true.


  1. Statement (B):

For a 2px2p_x2px​ orbital, the boundary surface diagram consists of two lobes oriented along the xxx-axis with a nodal plane at the yzyzyz-plane.

The given figure is intended to represent the boundary surface diagram of the 2px2p_x2px​ orbital, so (B) is true.


  1. Statement (C):

In orbital wave functions, the signs +++ and −-− do not represent positive or negative charge. They indicate the phase (algebraic sign) of the wave function.

Therefore, (C) is false.


  1. Statement (D):

For the 2px2p_x2px​ orbital, the angular part is proportional to xxx. Hence the wave function becomes zero when x=0x=0x=0.

The plane x=0x=0x=0 is the yzyzyz-plane, not the xyxyxy-plane. So the wave function is zero everywhere in the yzyzyz-plane, not in the xyxyxy-plane.

Therefore, (D) is false.


  1. Conclusion:

True statements are:

  • (A)
  • (B)

So the correct option is:

A: (A) and (B) only\boxed{\text{A: (A) and (B) only}}A: (A) and (B) only​


  1. Comparison with stored correct answer:

Stored correct answer = A

Our derived answer = A

Hence, they agree.

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