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Redox Reactions question

2023 · 25 Jan · Shift 1 · Q14
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Redox Reactions question

2023 · 25 Jan · Shift 1 · Q14

JEE MainChemistryRedox ReactionsNumerical+4 / −1
The density of a monobasic strong acid (Molar mass 24.2 g/mol) is 1.21 kg/L. The volume of its solution required for the complete neutralization of 25 mL of 0.24 M NaOH is ‾×\underline{\hspace{2cm}}\times​× 10 −2^{-2}−2 mL (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 12

  1. Given data
  • Monobasic strong acid
  • Molar mass of acid =24.2 g mol−1= 24.2\,\text{g mol}^{-1}=24.2g mol−1
  • Density of acid solution =1.21 kg L−1=1210 g L−1= 1.21\,\text{kg L}^{-1} = 1210\,\text{g L}^{-1}=1.21kg L−1=1210g L−1
  • Volume of NaOH =25 mL=0.025 L= 25\,\text{mL} = 0.025\,\text{L}=25mL=0.025L
  • Molarity of NaOH =0.24 M= 0.24\,\text{M}=0.24M
  1. Find moles of NaOH

Since, n=M×Vn = M \times Vn=M×V

So, n(NaOH)=0.24×0.025=0.006 moln(\text{NaOH}) = 0.24 \times 0.025 = 0.006\,\text{mol}n(NaOH)=0.24×0.025=0.006mol

  1. Neutralization stoichiometry

The acid is monobasic, so it provides one H+\text{H}^+H+ per mole.

Neutralization reaction: HA+NaOH→NaA+H2O\text{HA} + \text{NaOH} \rightarrow \text{NaA} + \text{H}_2\text{O}HA+NaOH→NaA+H2​O

Thus, molar ratio is 1:11:11:1.

Hence, required moles of acid: n(acid)=0.006 moln(\text{acid}) = 0.006\,\text{mol}n(acid)=0.006mol

  1. Find molarity of the acid from density and molar mass

Assuming the given strong acid is taken as pure liquid acid, mass of 1 L1\,\text{L}1L acid is: 1210 g1210\,\text{g}1210g

Number of moles in 1 L1\,\text{L}1L: M=121024.2=50 mol L−1M = \frac{1210}{24.2} = 50\,\text{mol L}^{-1}M=24.21210​=50mol L−1

So, molarity of acid =50 M= 50\,\text{M}=50M.

  1. Find volume of acid required

Using, V=nMV = \frac{n}{M}V=Mn​

V=0.00650=1.2×10−4 LV = \frac{0.006}{50} = 1.2 \times 10^{-4}\,\text{L}V=500.006​=1.2×10−4L

Convert to mL: 1.2×10−4×1000=0.12 mL1.2 \times 10^{-4} \times 1000 = 0.12\,\text{mL}1.2×10−4×1000=0.12mL

  1. Express in the required form

We need: ‾×10−2 mL\underline{\hspace{1cm}} \times 10^{-2}\,\text{mL}​×10−2mL

Now, 0.12 mL=12×10−2 mL0.12\,\text{mL} = 12 \times 10^{-2}\,\text{mL}0.12mL=12×10−2mL

So the required integer is: 12\boxed{12}12​

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